Research output: Contribution to journal › Article › peer-review
Addition of bromotrichloromethane and tetrachloromethane to alkenes in the presence of palladium(II) complexes begins with single-electron transfer from the palladium atom to polyhalomethane molecule, followed by fragmentation of the radical anion thus formed and generation of trichloromethyl radical. Halogen transfer to a carbon-centered radical arising from addition of trichloromethyl radical at the double bond occurs both from the polyhalomethane molecule and from halide palladium complex.
Original language | English |
---|---|
Pages (from-to) | 933-946 |
Number of pages | 14 |
Journal | Russian Journal of Organic Chemistry |
Volume | 39 |
Issue number | 7 |
DOIs | |
State | Published - Jul 2003 |
ID: 87469671