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Adamantylcalixarenes with CMPO groups at the wide rim: synthesis and extraction of lanthanides and actinides. / Motornaya, Alina; Vatsouro, Ivan; Shokova, Elvira; Hubscher-Bruder, Véronique; Alyapyshev, Mikhail; Babain, Vasily; Karavan, Maria; Arnaud-Neu, Françoise; Böhmer, Volker; Kovalev, Vladimir.

In: Tetrahedron, Vol. 63, No. 22, 28.05.2007, p. 4748-4755.

Research output: Contribution to journal › Article › peer-review

Harvard

Motornaya, A, Vatsouro, I, Shokova, E, Hubscher-Bruder, V, Alyapyshev, M, Babain, V, Karavan, M, Arnaud-Neu, F, Böhmer, V & Kovalev, V 2007, 'Adamantylcalixarenes with CMPO groups at the wide rim: synthesis and extraction of lanthanides and actinides', Tetrahedron, vol. 63, no. 22, pp. 4748-4755. https://doi.org/10.1016/j.tet.2007.03.088

APA

Motornaya, A., Vatsouro, I., Shokova, E., Hubscher-Bruder, V., Alyapyshev, M., Babain, V., Karavan, M., Arnaud-Neu, F., Böhmer, V., & Kovalev, V. (2007). Adamantylcalixarenes with CMPO groups at the wide rim: synthesis and extraction of lanthanides and actinides. Tetrahedron, 63(22), 4748-4755. https://doi.org/10.1016/j.tet.2007.03.088

Vancouver

Motornaya A, Vatsouro I, Shokova E, Hubscher-Bruder V, Alyapyshev M, Babain V et al. Adamantylcalixarenes with CMPO groups at the wide rim: synthesis and extraction of lanthanides and actinides. Tetrahedron. 2007 May 28;63(22):4748-4755. https://doi.org/10.1016/j.tet.2007.03.088

Author

Motornaya, Alina ; Vatsouro, Ivan ; Shokova, Elvira ; Hubscher-Bruder, Véronique ; Alyapyshev, Mikhail ; Babain, Vasily ; Karavan, Maria ; Arnaud-Neu, Françoise ; Böhmer, Volker ; Kovalev, Vladimir. / Adamantylcalixarenes with CMPO groups at the wide rim: synthesis and extraction of lanthanides and actinides. In: Tetrahedron. 2007 ; Vol. 63, No. 22. pp. 4748-4755.

BibTeX

@article{2c58aaed15a74589a11ffc6ddd5af5cb,
title = "Adamantylcalixarenes with CMPO groups at the wide rim: synthesis and extraction of lanthanides and actinides",
abstract = "Starting from p-adamantylcalix[4]- and [6]arenes functionalized with carboxylic acid or ester groups at the adamantane nuclei, carbamoylmethylphosphine oxide (CMPO)-containing ligands of a novel type were synthesized. They were studied as extractants for a series of f-block elements including radioactive 152Eu(III), 241Am(III), 233U(VI), and 239Pu(IV). Tetrameric ligand 4b in which CMPO residues are connected to adamantane nuclei through methylene groups gave the best extraction results for lanthanides and actinides. For all the ligands the extraction efficiency does not decrease at higher nitric acid concentration. Although the discrimination between trivalent actinides and lanthanides is not good, all ligands are highly selective for thorium(IV) with the best separation factor achieved in the case of hexameric ligand 5 (DTh/DLn>24). {\textcopyright} 2007 Elsevier Ltd. All rights reserved.",
author = "Alina Motornaya and Ivan Vatsouro and Elvira Shokova and V{\'e}ronique Hubscher-Bruder and Mikhail Alyapyshev and Vasily Babain and Maria Karavan and Fran{\c c}oise Arnaud-Neu and Volker B{\"o}hmer and Vladimir Kovalev",
year = "2007",
month = may,
day = "28",
doi = "10.1016/j.tet.2007.03.088",
language = "English",
volume = "63",
pages = "4748--4755",
journal = "Tetrahedron",
issn = "0040-4020",
publisher = "Elsevier",
number = "22",

}

RIS

TY - JOUR

T1 - Adamantylcalixarenes with CMPO groups at the wide rim: synthesis and extraction of lanthanides and actinides

AU - Motornaya, Alina

AU - Vatsouro, Ivan

AU - Shokova, Elvira

AU - Hubscher-Bruder, Véronique

AU - Alyapyshev, Mikhail

AU - Babain, Vasily

AU - Karavan, Maria

AU - Arnaud-Neu, Françoise

AU - Böhmer, Volker

AU - Kovalev, Vladimir

PY - 2007/5/28

Y1 - 2007/5/28

N2 - Starting from p-adamantylcalix[4]- and [6]arenes functionalized with carboxylic acid or ester groups at the adamantane nuclei, carbamoylmethylphosphine oxide (CMPO)-containing ligands of a novel type were synthesized. They were studied as extractants for a series of f-block elements including radioactive 152Eu(III), 241Am(III), 233U(VI), and 239Pu(IV). Tetrameric ligand 4b in which CMPO residues are connected to adamantane nuclei through methylene groups gave the best extraction results for lanthanides and actinides. For all the ligands the extraction efficiency does not decrease at higher nitric acid concentration. Although the discrimination between trivalent actinides and lanthanides is not good, all ligands are highly selective for thorium(IV) with the best separation factor achieved in the case of hexameric ligand 5 (DTh/DLn>24). © 2007 Elsevier Ltd. All rights reserved.

AB - Starting from p-adamantylcalix[4]- and [6]arenes functionalized with carboxylic acid or ester groups at the adamantane nuclei, carbamoylmethylphosphine oxide (CMPO)-containing ligands of a novel type were synthesized. They were studied as extractants for a series of f-block elements including radioactive 152Eu(III), 241Am(III), 233U(VI), and 239Pu(IV). Tetrameric ligand 4b in which CMPO residues are connected to adamantane nuclei through methylene groups gave the best extraction results for lanthanides and actinides. For all the ligands the extraction efficiency does not decrease at higher nitric acid concentration. Although the discrimination between trivalent actinides and lanthanides is not good, all ligands are highly selective for thorium(IV) with the best separation factor achieved in the case of hexameric ligand 5 (DTh/DLn>24). © 2007 Elsevier Ltd. All rights reserved.

UR - http://www.scopus.com/inward/record.url?scp=34247198877&partnerID=8YFLogxK

U2 - 10.1016/j.tet.2007.03.088

DO - 10.1016/j.tet.2007.03.088

M3 - Article

AN - SCOPUS:34247198877

VL - 63

SP - 4748

EP - 4755

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 22

ER -

ID: 114019598