• Udeep Chawla
  • Suchithranga M. D. C. Perera
  • Steven D. E. Fried
  • Anna R. Eitel
  • Blake Mertz
  • Nipuna Weerasinghe
  • Michael C. Pitman
  • Andrey Struts
  • M.F. Brown
Visual rhodopsin is an important archetype for G-protein-coupled receptors, which are membrane proteins implicated in cellular signal transduction. Herein, we show experimentally that approximately 80 water molecules flood rhodopsin upon light absorption to form a solvent-swollen active state. An influx of mobile water is necessary for activating the photoreceptor, and this finding is supported by molecular dynamics (MD) simulations. Combined force-based measurements involving osmotic and hydrostatic pressure indicate the expansion occurs by changes in cavity volumes, together with greater hydration in the active metarhodopsin-II state. Moreover, we discovered that binding and release of the C-terminal helix of transducin is coupled to hydration changes as may occur in visual signal amplification. Hydration-dehydration explains signaling by a dynamic allosteric mechanism, in which the soft membrane matter (lipids and water) has a pivotal role in the catalytic G-protein cycle.
Translated title of the contributionАктивация рецептора сопряженного с Г-белком родопсина водой
Original languageEnglish
Pages (from-to)2288-2295
Number of pages8
JournalAngewandte Chemie - International Edition
Volume60
Issue number5
Early online date28 Jun 2020
DOIs
StatePublished - 1 Feb 2021

    Research areas

  • GPCRs, membrane lipids, membrane proteins, osmotic stress, rhodopsin, CRYSTAL-STRUCTURE, METARHODOPSIN, RETINAL LIGAND, RELAXATION, INTERNAL HYDRATION, PRESSURE DENATURATION, VOLUMETRIC PROPERTIES, OPIOID RECEPTOR, DYNAMICS, REVEALS CONFORMATIONAL EQUILIBRIA

    Scopus subject areas

  • Chemistry(all)
  • Catalysis

ID: 60590991