Research output: Chapter in Book/Report/Conference proceeding › Chapter › Research › peer-review
Acids with chiral molecules as essential organic compounds of biogenic–abiogenic systems. / Kotelnikova, Elena N.; Isakov, Anton I.; Kryuchkova, Lyudmila Yu.; Zolotarev, Andrey A.; Bocharov, Sergey N.; Lorenz, Heike.
Lecture Notes in Earth System Sciences: Conference proceedings. ed. / Olga V. Frank-Kamenetskaya; Dmitry Yu. Vlasov; Elena G. Panova; Sofia N. Lessovaia. Cham : Springer Nature, 2020. p. 695-719 (Lecture Notes in Earth System Sciences).Research output: Chapter in Book/Report/Conference proceeding › Chapter › Research › peer-review
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TY - CHAP
T1 - Acids with chiral molecules as essential organic compounds of biogenic–abiogenic systems
AU - Kotelnikova, Elena N.
AU - Isakov, Anton I.
AU - Kryuchkova, Lyudmila Yu.
AU - Zolotarev, Andrey A.
AU - Bocharov, Sergey N.
AU - Lorenz, Heike
N1 - Conference code: VI
PY - 2020
Y1 - 2020
N2 - The present review generalizes results of a comprehensive experimental study (by means of PXRD, SCXRD, TRPXRD, DSC, IR) of six chiral systems. These are enantiomeric systems of a single substance: (1) the system with a eutectic point (S- and R-E3ClMA), (2) the system forming a binary compound (l- and d-phenylglycine), and (3) the system forming equimolar and non-equimolar discrete compounds (S- and R-malic acid). Also these are diastereomeric systems and a system composed of enantiomers of different substances: (4) the diastereomeric system with continuous solid solutions (l- and l-allo-threonine), and (5) the diastereomeric system with a eutectic point (d- and l-allo-threonine), and (6) the system of enantiomers of different substances (l-valine and l-isoleucine) which contains a non-equimolar discrete compound. Crystal structures of discrete equimolar and non-equimolar homomolecular and heteromolecular compounds found in the systems under discussion are described. Also, polymorph diversity and the limits of solid solutions in such binary systems are discussed.
AB - The present review generalizes results of a comprehensive experimental study (by means of PXRD, SCXRD, TRPXRD, DSC, IR) of six chiral systems. These are enantiomeric systems of a single substance: (1) the system with a eutectic point (S- and R-E3ClMA), (2) the system forming a binary compound (l- and d-phenylglycine), and (3) the system forming equimolar and non-equimolar discrete compounds (S- and R-malic acid). Also these are diastereomeric systems and a system composed of enantiomers of different substances: (4) the diastereomeric system with continuous solid solutions (l- and l-allo-threonine), and (5) the diastereomeric system with a eutectic point (d- and l-allo-threonine), and (6) the system of enantiomers of different substances (l-valine and l-isoleucine) which contains a non-equimolar discrete compound. Crystal structures of discrete equimolar and non-equimolar homomolecular and heteromolecular compounds found in the systems under discussion are described. Also, polymorph diversity and the limits of solid solutions in such binary systems are discussed.
KW - Chiral molecules
KW - Non-equimolar compounds
KW - Organic acids
KW - Phase diagrams
KW - Racemates
KW - Solid solutions
UR - http://www.scopus.com/inward/record.url?scp=85072069430&partnerID=8YFLogxK
U2 - 10.1007/978-3-030-21614-6_37
DO - 10.1007/978-3-030-21614-6_37
M3 - Chapter
AN - SCOPUS:85072069430
SN - 9783030216139
T3 - Lecture Notes in Earth System Sciences
SP - 695
EP - 719
BT - Lecture Notes in Earth System Sciences
A2 - Frank-Kamenetskaya, Olga V.
A2 - Vlasov, Dmitry Yu.
A2 - Panova, Elena G.
A2 - Lessovaia, Sofia N.
PB - Springer Nature
CY - Cham
Y2 - 24 September 2018 through 27 September 2018
ER -
ID: 46302734