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A statistical analysis of the wavenumbers of triplet rovibronic transitions of the D2 molecule : I. the estimation of experimental errors. / Lavrov, B. P.; Umrikhin, I. S.

In: Russian Journal of Physical Chemistry B, Vol. 3, No. 1, 01.02.2009, p. 1-10.

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@article{1fc250b0ec7242e399f5446222f9098b,
title = "A statistical analysis of the wavenumbers of triplet rovibronic transitions of the D2 molecule: I. the estimation of experimental errors",
abstract = "A statistical analysis of all the published experimental data on the wavenumbers of rovibronic optical transitions of the D2 molecule was performed for the first time. We used the optimization method of analysis (B.P. Lavrov and M.S. Ryazanov, JETP Lett. 81 (8), 371 (2005)), which allowed experimental errors to be estimated independently. 3588 of 3822 data (=94%) obtained by different methods in different works were found to be in excellent agreement with each other. It was shown that these data can be divided into 19 groups of uniformly precise experimental results. Experimental errors were determined for each of these groups. This created prerequisites for obtaining optimal energy values for all the triplet rovibronic states of D2 studied experimentally. 234 data (for 228 lines) were found to be in strong contradiction with the others according to the Rydberg-Ritz combination principle. Additional experimental studies of the doubtful spectral lines are necessary.",
author = "Lavrov, {B. P.} and Umrikhin, {I. S.}",
year = "2009",
month = feb,
day = "1",
doi = "10.1134/S1990793109010011",
language = "English",
volume = "3",
pages = "1--10",
journal = "Russian Journal of Physical Chemistry B",
issn = "1990-7931",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "1",

}

RIS

TY - JOUR

T1 - A statistical analysis of the wavenumbers of triplet rovibronic transitions of the D2 molecule

T2 - I. the estimation of experimental errors

AU - Lavrov, B. P.

AU - Umrikhin, I. S.

PY - 2009/2/1

Y1 - 2009/2/1

N2 - A statistical analysis of all the published experimental data on the wavenumbers of rovibronic optical transitions of the D2 molecule was performed for the first time. We used the optimization method of analysis (B.P. Lavrov and M.S. Ryazanov, JETP Lett. 81 (8), 371 (2005)), which allowed experimental errors to be estimated independently. 3588 of 3822 data (=94%) obtained by different methods in different works were found to be in excellent agreement with each other. It was shown that these data can be divided into 19 groups of uniformly precise experimental results. Experimental errors were determined for each of these groups. This created prerequisites for obtaining optimal energy values for all the triplet rovibronic states of D2 studied experimentally. 234 data (for 228 lines) were found to be in strong contradiction with the others according to the Rydberg-Ritz combination principle. Additional experimental studies of the doubtful spectral lines are necessary.

AB - A statistical analysis of all the published experimental data on the wavenumbers of rovibronic optical transitions of the D2 molecule was performed for the first time. We used the optimization method of analysis (B.P. Lavrov and M.S. Ryazanov, JETP Lett. 81 (8), 371 (2005)), which allowed experimental errors to be estimated independently. 3588 of 3822 data (=94%) obtained by different methods in different works were found to be in excellent agreement with each other. It was shown that these data can be divided into 19 groups of uniformly precise experimental results. Experimental errors were determined for each of these groups. This created prerequisites for obtaining optimal energy values for all the triplet rovibronic states of D2 studied experimentally. 234 data (for 228 lines) were found to be in strong contradiction with the others according to the Rydberg-Ritz combination principle. Additional experimental studies of the doubtful spectral lines are necessary.

UR - http://www.scopus.com/inward/record.url?scp=67650503717&partnerID=8YFLogxK

U2 - 10.1134/S1990793109010011

DO - 10.1134/S1990793109010011

M3 - Article

AN - SCOPUS:67650503717

VL - 3

SP - 1

EP - 10

JO - Russian Journal of Physical Chemistry B

JF - Russian Journal of Physical Chemistry B

SN - 1990-7931

IS - 1

ER -

ID: 36192830