DOI

  • Vanessa M. Koch
  • Maïssa K.S. Barr
  • Pascal Büttner
  • Ignacio Mínguez-Bacho
  • Dirk Döhler
  • Bettina Winzer
  • Elisabeth Reinhardt
  • Doris Segets
  • Julien Bachmann

We present a procedure to grow thin films of lead sulfide (PbS) with 'solution Atomic Layer Deposition' (sALD), a technique which transfers the principles of ALD from the gas phase (gALD) to liquid processing. PbS thin films are successfully deposited on planar and porous substrates with a procedure that exhibits the unique ALD characteristics of self-limiting surface chemistry and linear growth at room temperature. The polycrystalline p-type PbS films are stoichiometric and pure. They are converted to the hybrid perovskite methylammonium iodoplumbate (methylammonium lead iodide, MAPI, CH3NH3PbI3) by annealing to 150 °C in the presence of vapors from methylammonium iodide (MAI).

Original languageEnglish
Pages (from-to)25112-25119
Number of pages8
JournalJournal of Materials Chemistry A
Volume7
Issue number43
DOIs
StatePublished - 2019

    Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

ID: 77894561