DOI

A series of [Ir(C^N) 2(NN)][PF 6] complexes in which NN is 5-(4-ethynylphenyl)-2,2′-bipyridine has been synthesized and characterized by spectroscopic methods. All novel complexes exhibit unique singlet-triplet dual emission in solution with two well-separated emission bands. The mechanism of dual emission has been elucidated on the basis of experimental data and confirmed by TDDFT calculations.

Original languageEnglish
Pages (from-to)7578-7586
Number of pages9
JournalDalton Transactions
Volume47
Issue number22
DOIs
StatePublished - 14 Jun 2018

    Scopus subject areas

  • Inorganic Chemistry

    Research areas

  • BIOLOGICAL PROBES, ELECTROLUMINESCENCE, EMITTING ELECTROCHEMICAL-CELLS, EXCITED-STATES, IR(III) COMPLEXES, LIGANDS SYNTHESIS, LIVING CELLS, LUMINESCENCE, PHOSPHORESCENT, PHOTOPHYSICAL PROPERTIES

ID: 28195738