Research output: Contribution to journal › Article › peer-review
A rapid version of standardless stripping voltammetry for determining mercury in aqueous solutions. / Tsapko, Yu V.; Ermakov, S. S.; Moskvin, L. N.
In: Journal of Analytical Chemistry, Vol. 63, No. 10, 01.10.2008, p. 971-974.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - A rapid version of standardless stripping voltammetry for determining mercury in aqueous solutions
AU - Tsapko, Yu V.
AU - Ermakov, S. S.
AU - Moskvin, L. N.
PY - 2008/10/1
Y1 - 2008/10/1
N2 - It was shown that mercury(II) in aqueous solutions can be determined by standardless stripping voltammetry based on the determination of the coulometric constant of the electrochemical cell. This approach considerably reduces the analysis time in comparison to the known analogs. The coulometric constants were found for electrochemical cells with a gold and a gold-graphite film electrodes in solutions of different volumes. The optimum time of preelectrolysis was determined for measurements using the proposed method.
AB - It was shown that mercury(II) in aqueous solutions can be determined by standardless stripping voltammetry based on the determination of the coulometric constant of the electrochemical cell. This approach considerably reduces the analysis time in comparison to the known analogs. The coulometric constants were found for electrochemical cells with a gold and a gold-graphite film electrodes in solutions of different volumes. The optimum time of preelectrolysis was determined for measurements using the proposed method.
UR - http://www.scopus.com/inward/record.url?scp=53149142474&partnerID=8YFLogxK
U2 - 10.1134/S1061934808100080
DO - 10.1134/S1061934808100080
M3 - Article
AN - SCOPUS:53149142474
VL - 63
SP - 971
EP - 974
JO - Journal of Analytical Chemistry
JF - Journal of Analytical Chemistry
SN - 1061-9348
IS - 10
ER -
ID: 36704675