Standard

A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I. / Volkov, Sergey N.; Charkin, Dmitri O.; Kireev, Vadim E.; Ugolkov, Valery L.; Krzhizhanovskaya, Maria G.; Tsvetov, Nikita S.; Vaitieva, Yulia A.; Aksenov, Sergey M.; Bubnova, Rimma S.

In: Solid State Sciences, Vol. 145, 107311, 01.11.2023.

Research output: Contribution to journal › Article › peer-review

Harvard

Volkov, SN, Charkin, DO, Kireev, VE, Ugolkov, VL, Krzhizhanovskaya, MG, Tsvetov, NS, Vaitieva, YA, Aksenov, SM & Bubnova, RS 2023, 'A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I', Solid State Sciences, vol. 145, 107311. https://doi.org/10.1016/j.solidstatesciences.2023.107311

APA

Volkov, S. N., Charkin, D. O., Kireev, V. E., Ugolkov, V. L., Krzhizhanovskaya, M. G., Tsvetov, N. S., Vaitieva, Y. A., Aksenov, S. M., & Bubnova, R. S. (2023). A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I. Solid State Sciences, 145, [107311]. https://doi.org/10.1016/j.solidstatesciences.2023.107311

Vancouver

Volkov SN, Charkin DO, Kireev VE, Ugolkov VL, Krzhizhanovskaya MG, Tsvetov NS et al. A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I. Solid State Sciences. 2023 Nov 1;145. 107311. https://doi.org/10.1016/j.solidstatesciences.2023.107311

Author

Volkov, Sergey N. ; Charkin, Dmitri O. ; Kireev, Vadim E. ; Ugolkov, Valery L. ; Krzhizhanovskaya, Maria G. ; Tsvetov, Nikita S. ; Vaitieva, Yulia A. ; Aksenov, Sergey M. ; Bubnova, Rimma S. / A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I. In: Solid State Sciences. 2023 ; Vol. 145.

BibTeX

@article{d5f63158156b4b26b8cdf567735b00fd,
title = "A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I",
abstract = "In this work, we present a new borate, Ag3B6O10Br, as well as thermal properties of two recently reported members of M3B6O10X family, Ag3B6O10(NO3) and Na3B6O10I. The structure of Ag3B6O10Br is non-centrosymmetric, Pnm21, and exhibits a new version of packing the ionic Ag–Br and covalent B–O frameworks. The non-centrosymmetry is induced by alternation of disordered and ordered borate “layers” normal to a. The Ag–Br sublattice is also strongly disordered and exhibits pronounced ahnarmonicity of thermal vibrations modeled using the Gram – Charlier series. Thermal behavior of Ag3B6O10Br, Ag3B6O10(NO3) and Na3B6O10I was characterized using variable-temperature powder X-ray diffraction and thermal analysis. The thermal behavior of Ag3B6O10Br (αa = −0.5, αb = −7.4, αc = 41.5 at 200°С), Ag3B6O10(NO3) (αa = 4.5, αb = 4.8, αc = 31.8 at 200°С), and Na3B6O10I (αa = 9.4, αb = −1.2, αc = 48.3 at 200°С) is strongly anisotropic due to the alignment of the hexaborate B6O13 groups in the structure.",
keywords = "Anharmonicity, Borates, Crystal structure, Salt-inclusion structure, Thermal expansion, Х-ray diffraction",
author = "Volkov, {Sergey N.} and Charkin, {Dmitri O.} and Kireev, {Vadim E.} and Ugolkov, {Valery L.} and Krzhizhanovskaya, {Maria G.} and Tsvetov, {Nikita S.} and Vaitieva, {Yulia A.} and Aksenov, {Sergey M.} and Bubnova, {Rimma S.}",
year = "2023",
month = nov,
day = "1",
doi = "10.1016/j.solidstatesciences.2023.107311",
language = "English",
volume = "145",
journal = "Solid State Sciences",
issn = "1293-2558",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I

AU - Volkov, Sergey N.

AU - Charkin, Dmitri O.

AU - Kireev, Vadim E.

AU - Ugolkov, Valery L.

AU - Krzhizhanovskaya, Maria G.

AU - Tsvetov, Nikita S.

AU - Vaitieva, Yulia A.

AU - Aksenov, Sergey M.

AU - Bubnova, Rimma S.

PY - 2023/11/1

Y1 - 2023/11/1

N2 - In this work, we present a new borate, Ag3B6O10Br, as well as thermal properties of two recently reported members of M3B6O10X family, Ag3B6O10(NO3) and Na3B6O10I. The structure of Ag3B6O10Br is non-centrosymmetric, Pnm21, and exhibits a new version of packing the ionic Ag–Br and covalent B–O frameworks. The non-centrosymmetry is induced by alternation of disordered and ordered borate “layers” normal to a. The Ag–Br sublattice is also strongly disordered and exhibits pronounced ahnarmonicity of thermal vibrations modeled using the Gram – Charlier series. Thermal behavior of Ag3B6O10Br, Ag3B6O10(NO3) and Na3B6O10I was characterized using variable-temperature powder X-ray diffraction and thermal analysis. The thermal behavior of Ag3B6O10Br (αa = −0.5, αb = −7.4, αc = 41.5 at 200°С), Ag3B6O10(NO3) (αa = 4.5, αb = 4.8, αc = 31.8 at 200°С), and Na3B6O10I (αa = 9.4, αb = −1.2, αc = 48.3 at 200°С) is strongly anisotropic due to the alignment of the hexaborate B6O13 groups in the structure.

AB - In this work, we present a new borate, Ag3B6O10Br, as well as thermal properties of two recently reported members of M3B6O10X family, Ag3B6O10(NO3) and Na3B6O10I. The structure of Ag3B6O10Br is non-centrosymmetric, Pnm21, and exhibits a new version of packing the ionic Ag–Br and covalent B–O frameworks. The non-centrosymmetry is induced by alternation of disordered and ordered borate “layers” normal to a. The Ag–Br sublattice is also strongly disordered and exhibits pronounced ahnarmonicity of thermal vibrations modeled using the Gram – Charlier series. Thermal behavior of Ag3B6O10Br, Ag3B6O10(NO3) and Na3B6O10I was characterized using variable-temperature powder X-ray diffraction and thermal analysis. The thermal behavior of Ag3B6O10Br (αa = −0.5, αb = −7.4, αc = 41.5 at 200°С), Ag3B6O10(NO3) (αa = 4.5, αb = 4.8, αc = 31.8 at 200°С), and Na3B6O10I (αa = 9.4, αb = −1.2, αc = 48.3 at 200°С) is strongly anisotropic due to the alignment of the hexaborate B6O13 groups in the structure.

KW - Anharmonicity

KW - Borates

KW - Crystal structure

KW - Salt-inclusion structure

KW - Thermal expansion

KW - Х-ray diffraction

UR - https://www.mendeley.com/catalogue/c80fe9ca-d95e-324d-952c-98c9331cacd7/

U2 - 10.1016/j.solidstatesciences.2023.107311

DO - 10.1016/j.solidstatesciences.2023.107311

M3 - Article

VL - 145

JO - Solid State Sciences

JF - Solid State Sciences

SN - 1293-2558

M1 - 107311

ER -

ID: 111863333