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@article{b0e02e68d2954f338201f2a518f2ca4b,
title = "A novel bis-triazole scaffold accessed via two tandem [3 + 2] cycloaddition events including an uncatalyzed, room temperature azide–alkyne click reaction",
abstract = "The previously described α-acetyl-α-diazomethanesulfonamide was employed in a three-component reaction with azide-containing benzaldehydes and propargylamines. Besides the initial formation of the triazole core, the reaction proceeded further, in uncatalyzed fashion at room temperature and yielded, after intramolecular azide–alkyne click reaction novel, structurally intriguing bistriazoles.",
keywords = "α-acetyl-α-diazomethane sulfonamide, intramolecular click reaction, uncatalyzed, room temperature, 1,2,3-triazoles",
author = "Ksenia Malkova and Andrey Bubyrev and Vasilisa Krivovicheva and Dmitry Dar{\textquoteright}in and Alexander Bunev and Mikhail Krasavin",
year = "2022",
month = dec,
doi = "https://doi.org/10.3762/bjoc.18.175",
language = "English",
pages = "1636--1641",
journal = "Beilstein Journal of Organic Chemistry",
issn = "1860-5397",
publisher = "Beilstein-Institut Zur Forderung der Chemischen Wissenschaften",
number = "18",

}

RIS

TY - JOUR

T1 - A novel bis-triazole scaffold accessed via two tandem [3 + 2] cycloaddition events including an uncatalyzed, room temperature azide–alkyne click reaction

AU - Malkova, Ksenia

AU - Bubyrev, Andrey

AU - Krivovicheva, Vasilisa

AU - Dar’in, Dmitry

AU - Bunev, Alexander

AU - Krasavin, Mikhail

PY - 2022/12

Y1 - 2022/12

N2 - The previously described α-acetyl-α-diazomethanesulfonamide was employed in a three-component reaction with azide-containing benzaldehydes and propargylamines. Besides the initial formation of the triazole core, the reaction proceeded further, in uncatalyzed fashion at room temperature and yielded, after intramolecular azide–alkyne click reaction novel, structurally intriguing bistriazoles.

AB - The previously described α-acetyl-α-diazomethanesulfonamide was employed in a three-component reaction with azide-containing benzaldehydes and propargylamines. Besides the initial formation of the triazole core, the reaction proceeded further, in uncatalyzed fashion at room temperature and yielded, after intramolecular azide–alkyne click reaction novel, structurally intriguing bistriazoles.

KW - α-acetyl-α-diazomethane sulfonamide

KW - intramolecular click reaction

KW - uncatalyzed

KW - room temperature

KW - 1,2,3-triazoles

U2 - https://doi.org/10.3762/bjoc.18.175

DO - https://doi.org/10.3762/bjoc.18.175

M3 - Article

SP - 1636

EP - 1641

JO - Beilstein Journal of Organic Chemistry

JF - Beilstein Journal of Organic Chemistry

SN - 1860-5397

IS - 18

ER -

ID: 101521916