Standard

A new deep eutectic solvent based on diphenylguanidine for the effective extraction of pertechnetate anion. / Leksina, U.M.; Shishov, A.Y.; Mulloyarova, V.V.; Puzyk, A.M.; Tolstoy, P.M.; Vokuev, M.F.; Glushkov, E.D.; Petrov, V.G.; Matveev, P.I.

In: Separation and Purification Technology, Vol. 316, 123824, 01.07.2023.

Research output: Contribution to journal › Article › peer-review

Harvard

Leksina, UM, Shishov, AY, Mulloyarova, VV, Puzyk, AM, Tolstoy, PM, Vokuev, MF, Glushkov, ED, Petrov, VG & Matveev, PI 2023, 'A new deep eutectic solvent based on diphenylguanidine for the effective extraction of pertechnetate anion', Separation and Purification Technology, vol. 316, 123824. https://doi.org/10.1016/j.seppur.2023.123824

APA

Leksina, U. M., Shishov, A. Y., Mulloyarova, V. V., Puzyk, A. M., Tolstoy, P. M., Vokuev, M. F., Glushkov, E. D., Petrov, V. G., & Matveev, P. I. (2023). A new deep eutectic solvent based on diphenylguanidine for the effective extraction of pertechnetate anion. Separation and Purification Technology, 316, [123824]. https://doi.org/10.1016/j.seppur.2023.123824

Vancouver

Leksina UM, Shishov AY, Mulloyarova VV, Puzyk AM, Tolstoy PM, Vokuev MF et al. A new deep eutectic solvent based on diphenylguanidine for the effective extraction of pertechnetate anion. Separation and Purification Technology. 2023 Jul 1;316. 123824. https://doi.org/10.1016/j.seppur.2023.123824

Author

Leksina, U.M. ; Shishov, A.Y. ; Mulloyarova, V.V. ; Puzyk, A.M. ; Tolstoy, P.M. ; Vokuev, M.F. ; Glushkov, E.D. ; Petrov, V.G. ; Matveev, P.I. / A new deep eutectic solvent based on diphenylguanidine for the effective extraction of pertechnetate anion. In: Separation and Purification Technology. 2023 ; Vol. 316.

BibTeX

@article{b0ce50b2a6f44eeb899a92ac32e14d0c,
title = "A new deep eutectic solvent based on diphenylguanidine for the effective extraction of pertechnetate anion",
abstract = "In this work, for the first time, a new class of deep eutectic solvents has been synthesized and applied for the efficient extraction of pertechnetate anion from imitators of real media from which pertechnetate removal is needed: high-level waste imitator and sea water imitator. Diphenyl guanidine was studied as a hydrogen bond acceptor, which exhibits a high extraction ability for pertechnetate anion separation. Natural fatty acid and natural terpene were studied as hydrogen bond donors. The structure, properties, viscosity and stability of the obtained eutectic solvents were studied. Also, the radiation resistance of the obtained solvents was studied from the point of view of distribution ratio saving. It was shown that the new class of solvents has a high radiation resistance and efficiently extracts pertechnetate anion even from acidic media in high-temperature extraction process and can be the first step platform for solving technological and radiation safety problems.",
keywords = "Anion receptor, Deep eutectic solvents, Extraction, Nuclear waste, Solvent extraction, Technetium",
author = "U.M. Leksina and A.Y. Shishov and V.V. Mulloyarova and A.M. Puzyk and P.M. Tolstoy and M.F. Vokuev and E.D. Glushkov and V.G. Petrov and P.I. Matveev",
year = "2023",
month = jul,
day = "1",
doi = "10.1016/j.seppur.2023.123824",
language = "English",
volume = "316",
journal = "Separation and Purification Technology",
issn = "1383-5866",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - A new deep eutectic solvent based on diphenylguanidine for the effective extraction of pertechnetate anion

AU - Leksina, U.M.

AU - Shishov, A.Y.

AU - Mulloyarova, V.V.

AU - Puzyk, A.M.

AU - Tolstoy, P.M.

AU - Vokuev, M.F.

AU - Glushkov, E.D.

AU - Petrov, V.G.

AU - Matveev, P.I.

PY - 2023/7/1

Y1 - 2023/7/1

N2 - In this work, for the first time, a new class of deep eutectic solvents has been synthesized and applied for the efficient extraction of pertechnetate anion from imitators of real media from which pertechnetate removal is needed: high-level waste imitator and sea water imitator. Diphenyl guanidine was studied as a hydrogen bond acceptor, which exhibits a high extraction ability for pertechnetate anion separation. Natural fatty acid and natural terpene were studied as hydrogen bond donors. The structure, properties, viscosity and stability of the obtained eutectic solvents were studied. Also, the radiation resistance of the obtained solvents was studied from the point of view of distribution ratio saving. It was shown that the new class of solvents has a high radiation resistance and efficiently extracts pertechnetate anion even from acidic media in high-temperature extraction process and can be the first step platform for solving technological and radiation safety problems.

AB - In this work, for the first time, a new class of deep eutectic solvents has been synthesized and applied for the efficient extraction of pertechnetate anion from imitators of real media from which pertechnetate removal is needed: high-level waste imitator and sea water imitator. Diphenyl guanidine was studied as a hydrogen bond acceptor, which exhibits a high extraction ability for pertechnetate anion separation. Natural fatty acid and natural terpene were studied as hydrogen bond donors. The structure, properties, viscosity and stability of the obtained eutectic solvents were studied. Also, the radiation resistance of the obtained solvents was studied from the point of view of distribution ratio saving. It was shown that the new class of solvents has a high radiation resistance and efficiently extracts pertechnetate anion even from acidic media in high-temperature extraction process and can be the first step platform for solving technological and radiation safety problems.

KW - Anion receptor

KW - Deep eutectic solvents

KW - Extraction

KW - Nuclear waste

KW - Solvent extraction

KW - Technetium

UR - https://www.mendeley.com/catalogue/365372b5-e838-3585-a5a7-5dc4ab9dc97b/

U2 - 10.1016/j.seppur.2023.123824

DO - 10.1016/j.seppur.2023.123824

M3 - Article

VL - 316

JO - Separation and Purification Technology

JF - Separation and Purification Technology

SN - 1383-5866

M1 - 123824

ER -

ID: 111862870