Research output: Contribution to journal › Article › peer-review
A new contribution to the lead and strontium perrhenate chemistry: synthesis and crystal structures of Pb(ReO4)Cl·2H2O, Pb(ReO4)2·2H2O, {Pb4(OH)4}(ReO4)4·H2O, Sr(ReO4)2·H2O and Sr(ReO4)2·6H2O. / Чаркин, Дмитрий Олегович; Сийдра, Олег Иоханнесович; Назарчук, Евгений Васильевич; Борисов, Артем Сергеевич; Марковски, Мишел.
In: Structural Chemistry, Vol. 36, 02.04.2025, p. 2049–2059.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - A new contribution to the lead and strontium perrhenate chemistry: synthesis and crystal structures of Pb(ReO4)Cl·2H2O, Pb(ReO4)2·2H2O, {Pb4(OH)4}(ReO4)4·H2O, Sr(ReO4)2·H2O and Sr(ReO4)2·6H2O
AU - Чаркин, Дмитрий Олегович
AU - Сийдра, Олег Иоханнесович
AU - Назарчук, Евгений Васильевич
AU - Борисов, Артем Сергеевич
AU - Марковски, Мишел
PY - 2025/4/2
Y1 - 2025/4/2
N2 - Structures of a family of new hydrated and anhydrous perrhenates of lead and strontium have been determined. Sr(ReO4)2·H2O is isostructural to Ce(CrO4)2·H2O and Th(CrO4)2·H2O; Pb(ReO4)2·2H2O is analogous to Sr(ReO4)2·2H2O and Pb(TcO4)2·2H2O. The compounds Sr(ReO4)2·6H2O, Pb(ReO4)Cl·2H2O, and {Pb4(OH)4}(ReO4)4·H2O correspond to new structural architectures. We discuss the similarities and differences in the crystal structures of relatively simple inorganic salts containing tetrahedral oxoanions based on d-elements (MnO4−, TcO4−, ReO4−, CrO42−, and MoO42−); the analogies to tetrahedral p-based hydrido- or fluoroanions (BF4− and AlH4−) exist but are as yet rare.
AB - Structures of a family of new hydrated and anhydrous perrhenates of lead and strontium have been determined. Sr(ReO4)2·H2O is isostructural to Ce(CrO4)2·H2O and Th(CrO4)2·H2O; Pb(ReO4)2·2H2O is analogous to Sr(ReO4)2·2H2O and Pb(TcO4)2·2H2O. The compounds Sr(ReO4)2·6H2O, Pb(ReO4)Cl·2H2O, and {Pb4(OH)4}(ReO4)4·H2O correspond to new structural architectures. We discuss the similarities and differences in the crystal structures of relatively simple inorganic salts containing tetrahedral oxoanions based on d-elements (MnO4−, TcO4−, ReO4−, CrO42−, and MoO42−); the analogies to tetrahedral p-based hydrido- or fluoroanions (BF4− and AlH4−) exist but are as yet rare.
KW - Inorganic synthesis
KW - Lead
KW - Perrhenates
KW - Rhenium
KW - Strontium
UR - https://link.springer.com/article/10.1007/s11224-025-02485-8
UR - https://www.mendeley.com/catalogue/a82fd637-1ff9-3919-9fa5-5c1fdccbf0a0/
U2 - 10.1007/s11224-025-02485-8
DO - 10.1007/s11224-025-02485-8
M3 - Article
VL - 36
SP - 2049
EP - 2059
JO - Structural Chemistry
JF - Structural Chemistry
SN - 1040-0400
ER -
ID: 135630500