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@article{cabde527e6ed4aadbb5859ffb0e48e27,
title = "A new contribution to the lead and strontium perrhenate chemistry: synthesis and crystal structures of Pb(ReO4)Cl·2H2O, Pb(ReO4)2·2H2O, {Pb4(OH)4}(ReO4)4·H2O, Sr(ReO4)2·H2O and Sr(ReO4)2·6H2O",
abstract = "Structures of a family of new hydrated and anhydrous perrhenates of lead and strontium have been determined. Sr(ReO4)2·H2O is isostructural to Ce(CrO4)2·H2O and Th(CrO4)2·H2O; Pb(ReO4)2·2H2O is analogous to Sr(ReO4)2·2H2O and Pb(TcO4)2·2H2O. The compounds Sr(ReO4)2·6H2O, Pb(ReO4)Cl·2H2O, and {Pb4(OH)4}(ReO4)4·H2O correspond to new structural architectures. We discuss the similarities and differences in the crystal structures of relatively simple inorganic salts containing tetrahedral oxoanions based on d-elements (MnO4−, TcO4−, ReO4−, CrO42−, and MoO42−); the analogies to tetrahedral p-based hydrido- or fluoroanions (BF4− and AlH4−) exist but are as yet rare.",
keywords = "Inorganic synthesis, Lead, Perrhenates, Rhenium, Strontium",
author = "Чаркин, {Дмитрий Олегович} and Сийдра, {Олег Иоханнесович} and Назарчук, {Евгений Васильевич} and Борисов, {Артем Сергеевич} and Мишел Марковски",
year = "2025",
month = apr,
day = "2",
doi = "10.1007/s11224-025-02485-8",
language = "English",
volume = "36",
pages = "2049–2059",
journal = "Structural Chemistry",
issn = "1040-0400",
publisher = "Springer Nature",

}

RIS

TY - JOUR

T1 - A new contribution to the lead and strontium perrhenate chemistry: synthesis and crystal structures of Pb(ReO4)Cl·2H2O, Pb(ReO4)2·2H2O, {Pb4(OH)4}(ReO4)4·H2O, Sr(ReO4)2·H2O and Sr(ReO4)2·6H2O

AU - Чаркин, Дмитрий Олегович

AU - Сийдра, Олег Иоханнесович

AU - Назарчук, Евгений Васильевич

AU - Борисов, Артем Сергеевич

AU - Марковски, Мишел

PY - 2025/4/2

Y1 - 2025/4/2

N2 - Structures of a family of new hydrated and anhydrous perrhenates of lead and strontium have been determined. Sr(ReO4)2·H2O is isostructural to Ce(CrO4)2·H2O and Th(CrO4)2·H2O; Pb(ReO4)2·2H2O is analogous to Sr(ReO4)2·2H2O and Pb(TcO4)2·2H2O. The compounds Sr(ReO4)2·6H2O, Pb(ReO4)Cl·2H2O, and {Pb4(OH)4}(ReO4)4·H2O correspond to new structural architectures. We discuss the similarities and differences in the crystal structures of relatively simple inorganic salts containing tetrahedral oxoanions based on d-elements (MnO4−, TcO4−, ReO4−, CrO42−, and MoO42−); the analogies to tetrahedral p-based hydrido- or fluoroanions (BF4− and AlH4−) exist but are as yet rare.

AB - Structures of a family of new hydrated and anhydrous perrhenates of lead and strontium have been determined. Sr(ReO4)2·H2O is isostructural to Ce(CrO4)2·H2O and Th(CrO4)2·H2O; Pb(ReO4)2·2H2O is analogous to Sr(ReO4)2·2H2O and Pb(TcO4)2·2H2O. The compounds Sr(ReO4)2·6H2O, Pb(ReO4)Cl·2H2O, and {Pb4(OH)4}(ReO4)4·H2O correspond to new structural architectures. We discuss the similarities and differences in the crystal structures of relatively simple inorganic salts containing tetrahedral oxoanions based on d-elements (MnO4−, TcO4−, ReO4−, CrO42−, and MoO42−); the analogies to tetrahedral p-based hydrido- or fluoroanions (BF4− and AlH4−) exist but are as yet rare.

KW - Inorganic synthesis

KW - Lead

KW - Perrhenates

KW - Rhenium

KW - Strontium

UR - https://link.springer.com/article/10.1007/s11224-025-02485-8

UR - https://www.mendeley.com/catalogue/a82fd637-1ff9-3919-9fa5-5c1fdccbf0a0/

U2 - 10.1007/s11224-025-02485-8

DO - 10.1007/s11224-025-02485-8

M3 - Article

VL - 36

SP - 2049

EP - 2059

JO - Structural Chemistry

JF - Structural Chemistry

SN - 1040-0400

ER -

ID: 135630500