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A light-driven ultrafast sensor based on biocompatible solvatochromic metal-organic frameworks. / Milichko, Valentin; Burzak, Nikita; Bondarenko, Andrey B.; Dyachuk, Vyasheslav A.; Timofeeva, Maria; Kenzhebayeva, Yuliya; Bazhenova, Agniia; Lunev, Artem; Novikov, Alexander S.; Shipilovskikh, Sergei.

In: Materials Horizons, 15.11.2024.

Research output: Contribution to journalArticlepeer-review

Harvard

Milichko, V, Burzak, N, Bondarenko, AB, Dyachuk, VA, Timofeeva, M, Kenzhebayeva, Y, Bazhenova, A, Lunev, A, Novikov, AS & Shipilovskikh, S 2024, 'A light-driven ultrafast sensor based on biocompatible solvatochromic metal-organic frameworks', Materials Horizons. https://doi.org/10.1039/d4mh01264j

APA

Milichko, V., Burzak, N., Bondarenko, A. B., Dyachuk, V. A., Timofeeva, M., Kenzhebayeva, Y., Bazhenova, A., Lunev, A., Novikov, A. S., & Shipilovskikh, S. (2024). A light-driven ultrafast sensor based on biocompatible solvatochromic metal-organic frameworks. Materials Horizons. https://doi.org/10.1039/d4mh01264j

Vancouver

Milichko V, Burzak N, Bondarenko AB, Dyachuk VA, Timofeeva M, Kenzhebayeva Y et al. A light-driven ultrafast sensor based on biocompatible solvatochromic metal-organic frameworks. Materials Horizons. 2024 Nov 15. https://doi.org/10.1039/d4mh01264j

Author

Milichko, Valentin ; Burzak, Nikita ; Bondarenko, Andrey B. ; Dyachuk, Vyasheslav A. ; Timofeeva, Maria ; Kenzhebayeva, Yuliya ; Bazhenova, Agniia ; Lunev, Artem ; Novikov, Alexander S. ; Shipilovskikh, Sergei. / A light-driven ultrafast sensor based on biocompatible solvatochromic metal-organic frameworks. In: Materials Horizons. 2024.

BibTeX

@article{22ea1d8eb69546b7aec1829fe0544f80,
title = "A light-driven ultrafast sensor based on biocompatible solvatochromic metal-organic frameworks",
abstract = "The design of fast, endurant, and biocompatible porous frameworks with solvatochromism, aimed to addressing the multiple visual sensing of chemicals, still remains a challenge. Here, we report on a solvatochromic metal-organic framework (MOF) based on cobalt and trimesic acid. We examined its solvatochromism through the solvent exchange and revealed high selectivity to water/dimethylformamide combination. The color change over 50 cycles during the solvent exchange occurs for 0.1 s, being 2 orders of magnitude faster than for existing MOFs. Despite the cobalt content, toxicity assays in vivo and in vitro revealed high biocompatibility of the MOF. The latter allowed implementing the fastest, highly-endurant and biocompatible MOF-based visual sensor of humidity in a desiccator for storage of water-sensitive goods and chemicals. Finally, for such a sensor, we demonstrated its multiple uses through remote light-driven recovery that contributes to the sustainability of this functional MOF.",
author = "Valentin Milichko and Nikita Burzak and Bondarenko, {Andrey B.} and Dyachuk, {Vyasheslav A.} and Maria Timofeeva and Yuliya Kenzhebayeva and Agniia Bazhenova and Artem Lunev and Novikov, {Alexander S.} and Sergei Shipilovskikh",
year = "2024",
month = nov,
day = "15",
doi = "10.1039/d4mh01264j",
language = "English",
journal = "Materials Horizons",
issn = "2051-6347",
publisher = "Royal Society of Chemistry",

}

RIS

TY - JOUR

T1 - A light-driven ultrafast sensor based on biocompatible solvatochromic metal-organic frameworks

AU - Milichko, Valentin

AU - Burzak, Nikita

AU - Bondarenko, Andrey B.

AU - Dyachuk, Vyasheslav A.

AU - Timofeeva, Maria

AU - Kenzhebayeva, Yuliya

AU - Bazhenova, Agniia

AU - Lunev, Artem

AU - Novikov, Alexander S.

AU - Shipilovskikh, Sergei

PY - 2024/11/15

Y1 - 2024/11/15

N2 - The design of fast, endurant, and biocompatible porous frameworks with solvatochromism, aimed to addressing the multiple visual sensing of chemicals, still remains a challenge. Here, we report on a solvatochromic metal-organic framework (MOF) based on cobalt and trimesic acid. We examined its solvatochromism through the solvent exchange and revealed high selectivity to water/dimethylformamide combination. The color change over 50 cycles during the solvent exchange occurs for 0.1 s, being 2 orders of magnitude faster than for existing MOFs. Despite the cobalt content, toxicity assays in vivo and in vitro revealed high biocompatibility of the MOF. The latter allowed implementing the fastest, highly-endurant and biocompatible MOF-based visual sensor of humidity in a desiccator for storage of water-sensitive goods and chemicals. Finally, for such a sensor, we demonstrated its multiple uses through remote light-driven recovery that contributes to the sustainability of this functional MOF.

AB - The design of fast, endurant, and biocompatible porous frameworks with solvatochromism, aimed to addressing the multiple visual sensing of chemicals, still remains a challenge. Here, we report on a solvatochromic metal-organic framework (MOF) based on cobalt and trimesic acid. We examined its solvatochromism through the solvent exchange and revealed high selectivity to water/dimethylformamide combination. The color change over 50 cycles during the solvent exchange occurs for 0.1 s, being 2 orders of magnitude faster than for existing MOFs. Despite the cobalt content, toxicity assays in vivo and in vitro revealed high biocompatibility of the MOF. The latter allowed implementing the fastest, highly-endurant and biocompatible MOF-based visual sensor of humidity in a desiccator for storage of water-sensitive goods and chemicals. Finally, for such a sensor, we demonstrated its multiple uses through remote light-driven recovery that contributes to the sustainability of this functional MOF.

UR - https://www.mendeley.com/catalogue/21a39156-5dbb-3eb1-ae3e-a76ccc296ead/

U2 - 10.1039/d4mh01264j

DO - 10.1039/d4mh01264j

M3 - Article

JO - Materials Horizons

JF - Materials Horizons

SN - 2051-6347

ER -

ID: 127256362