The electron kinetic model of rocket exhaust dusty plasma is developed based on the Boltzmann equation. Additional electron-dust elastic and inelastic collision processes are included in the kinetic equation except for the electron-neutral collisions. The dust surface potential and electron density are calculated according to the dust charging balance equation and the quasineutrality condition. The electron energy distribution function (EEDF) is calculated by solving the kinetic equation numerically. It shows that the obtained EEDF results for different dust densities deviate from the Maxwellian distribution obviously. In addition, the dielectric properties of rocket exhausts based on the obtained non-Maxwellian EEDFs are analyzed for different dust and plasma parameters. It is shown that the relative permittivity based on the EEDFs obtained from the kinetic model is larger than that based on Maxwellian distribution, while for the conductivity and attenuation constant, they become smaller. As for the influence of dust particles on the dielectric properties, a high ratio of dust and neutral density (10^-9) leads to a smaller absolute value of relative permittivity, electrical conductivity, and attenuation constant for both Maxwellian distribution and EEDF obtained from the kinetic model. When the ratio is low (10^-10), the dust particles almost have no influence on the dielectric properties. Meanwhile, it can be seen that the existence of dust particles makes the difference in dielectric properties obtained from the calculated EEDFs and Maxwellian distribution smaller.