DOI

The proton spin-lattice relaxation time T1, in the nematic liquid crystal 4-pentyl-4′-cyanobiphenyl confined in a glassy porous mtrix has been measured in a wide Larmor frequency range of 1 · 102-2 · 107 Hz employing the fast field-cycling NMR technique. A strong influence of the restricted geometry on the character of the T1 dispersion was found. Our investigation clearly demonstrates the importance of the translationally induced molecular reorientations in inhomogeneous director field for the relaxation in the samples with 200 and 80 nm mean pore size. The experimental results are in a good agreement with the theoretical predictions. In the sample with 7 nm pore size the main contribution to the relaxation is ascribed to the slowing down of the molecular motion in the near-surface layer. Zero-field 1H NMR spectra of a microconfined liquid crystal are reported for the first time.

Original languageEnglish
Pages (from-to)363-381
Number of pages19
JournalApplied Magnetic Resonance
Volume15
Issue number3-4
DOIs
StatePublished - 1 Jan 1998

    Scopus subject areas

  • Atomic and Molecular Physics, and Optics

ID: 48950018