Research output: Contribution to journal › Comment/debate › peer-review
6,6′-{[ethane-1,2-diylbis(Azaneylylidene)] bis(methaneylylidene)}bis [2-(hexyloxy)phenolato] nickel(ii). / Лукьянов, Даниил Александрович; Борисова, Анна Сергеевна; Левин, Олег Владиславович.
In: MolBank, Vol. 2020, No. 4, M1174, 12.2020, p. 1-5.Research output: Contribution to journal › Comment/debate › peer-review
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TY - JOUR
T1 - 6,6′-{[ethane-1,2-diylbis(Azaneylylidene)] bis(methaneylylidene)}bis [2-(hexyloxy)phenolato] nickel(ii)
AU - Лукьянов, Даниил Александрович
AU - Борисова, Анна Сергеевна
AU - Левин, Олег Владиславович
N1 - Funding Information: Funding: This research was funded by Russian Scientific Foundation (RSF), grant number 19-19-00175. Funding Information: Acknowledgments:WethanktheResearchCenteFundr foring:MagneticThis research was fResonance, theunded by Center forRussian Scientific FChemical Analysisoundation and (RSF), grant number 19-19-00175. Publisher Copyright: © 2020 by the authors. Licensee MDPI, Basel, Switzerland. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/12
Y1 - 2020/12
N2 - Polymeric nickel complexes of salen ligands meet a wide range of applications in catalysis and electrochemistry. Because these polymers usually form very rigid films, the introduction of the conformationally flexible fragments in the corresponding monomers favors the amorphization and, thus, the mass transport. Herein we report a preparation of the hexyloxy-substituted monomeric NiSalen complex by the direct alkylation of the hydroxy-substituted complex. The resulting product was characterized by the1H and13C nuclear magnetic resonance (NMR), ESI-high resolution mass spectrometry (ESI-HRMS, and Fourier-transform infrared spectroscopy (FTIR). The crystal structure of the product was examined by an XRD, indicating the formation of the solvate with dichloromethane. The obtained product was found to be highly soluble in non-polar solvents, in contrast to typical NiSalens.
AB - Polymeric nickel complexes of salen ligands meet a wide range of applications in catalysis and electrochemistry. Because these polymers usually form very rigid films, the introduction of the conformationally flexible fragments in the corresponding monomers favors the amorphization and, thus, the mass transport. Herein we report a preparation of the hexyloxy-substituted monomeric NiSalen complex by the direct alkylation of the hydroxy-substituted complex. The resulting product was characterized by the1H and13C nuclear magnetic resonance (NMR), ESI-high resolution mass spectrometry (ESI-HRMS, and Fourier-transform infrared spectroscopy (FTIR). The crystal structure of the product was examined by an XRD, indicating the formation of the solvate with dichloromethane. The obtained product was found to be highly soluble in non-polar solvents, in contrast to typical NiSalens.
KW - Crystal structure
KW - Nickel salen
KW - Shiff base
UR - http://www.scopus.com/inward/record.url?scp=85097486176&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/f9a21831-b7e7-33a7-9b52-cc5c905594e5/
U2 - 10.3390/M1174
DO - 10.3390/M1174
M3 - Comment/debate
AN - SCOPUS:85097486176
VL - 2020
SP - 1
EP - 5
JO - MolBank
JF - MolBank
SN - 1422-8599
IS - 4
M1 - M1174
ER -
ID: 71867904