Research output: Contribution to journal › Article › peer-review
5-Vinyl-1H-Tetrazole. / Krygina, Daria ; Sivtsov, Eugene ; Pavlyukova , Yuliya ; Chernova , Ekaterina ; Skryl’nikova, Mariya ; Байгильдин, Вадим Азаматович; Пузык, Александра Михайловна; Oskorbyn , Alexander ; Trifonov, Rostislav ; Aleshunin , Pavel ; Ostrovskii , Vladimir .
In: MolBank, Vol. 2023, No. 1, M1565, 23.01.2023.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - 5-Vinyl-1H-Tetrazole
AU - Krygina, Daria
AU - Sivtsov, Eugene
AU - Pavlyukova , Yuliya
AU - Chernova , Ekaterina
AU - Skryl’nikova, Mariya
AU - Байгильдин, Вадим Азаматович
AU - Пузык, Александра Михайловна
AU - Oskorbyn , Alexander
AU - Trifonov, Rostislav
AU - Aleshunin , Pavel
AU - Ostrovskii , Vladimir
PY - 2023/1/23
Y1 - 2023/1/23
N2 - Highly purified 5-vinyl-1H-tetrazole was synthesized, which is in great demand in modern medicine and industry as a monomer for obtaining nitrogen-rich macromolecular compounds and a reagent for the complete synthesis of biological compounds. The molecular structure was studied experimentally with sequential X-ray diffraction analysis and theoretically with ab initio quantum chemical calculations. The data from differential scanning calorimetry, nuclear magnetic resonance (1H, 13C, 1H-15N, HMBC), high-resolution mass spectrometry and vibrational spectroscopy were analyzed. The results are useful for evaluating the possibility of extending the polymerization of 5-vinyl-1H-tetrazole to synthesize polymers with predictable molecular weight and thermodynamic parameters.
AB - Highly purified 5-vinyl-1H-tetrazole was synthesized, which is in great demand in modern medicine and industry as a monomer for obtaining nitrogen-rich macromolecular compounds and a reagent for the complete synthesis of biological compounds. The molecular structure was studied experimentally with sequential X-ray diffraction analysis and theoretically with ab initio quantum chemical calculations. The data from differential scanning calorimetry, nuclear magnetic resonance (1H, 13C, 1H-15N, HMBC), high-resolution mass spectrometry and vibrational spectroscopy were analyzed. The results are useful for evaluating the possibility of extending the polymerization of 5-vinyl-1H-tetrazole to synthesize polymers with predictable molecular weight and thermodynamic parameters.
UR - https://www.mendeley.com/catalogue/84b42808-c0eb-3450-8737-842d4282738c/
U2 - 10.3390/M1565
DO - 10.3390/M1565
M3 - Article
VL - 2023
JO - MolBank
JF - MolBank
SN - 1422-8599
IS - 1
M1 - M1565
ER -
ID: 102170369