[4+2] Dimerization of Arylmaleic Acids Imides on Solid Media

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[4+2] Dimerization of Arylmaleic Acids Imides on Solid Media. / Попова, Е.А.; Бойцов, Виталий Михайлович; Степаков, Александр Владимирович.

In: Russian Journal of General Chemistry, Vol. 94, No. 6, 01.06.2024, p. 1251–1256.

Research output: Contribution to journal › Article › peer-review

Author

Попова, Е.А. ; Бойцов, Виталий Михайлович ; Степаков, Александр Владимирович. / [4+2] Dimerization of Arylmaleic Acids Imides on Solid Media. In: Russian Journal of General Chemistry. 2024 ; Vol. 94, No. 6. pp. 1251–1256.

BibTeX

@article{635ff42a216d4249a02ab33f2e2f7562,

title = "[4+2] Dimerization of Arylmaleic Acids Imides on Solid Media",

abstract = "Abstract: The [4+2] dimerization of arylmaleic acid imides, which occurs in the presence of 3,5-dimethyl-1H-pyrazole on solid media under convection or microwave heating, has been studied. It was shown that dimerization proceeds stereoselectively with the formation of polycyclic compounds with a decahydrobenzo[e]pyrrolo[3,4-g]isoindole skeleton, predominantly of the endo-configuration. The best results in yields and stereoselectivity were achieved when reactions were carried out on silica gel under microwave activation conditions.",

keywords = "3,5-dimethyl-1H-pyrazole, [4+2] dimerization, arylmaleic acid imides, polycyclic compounds, reactions on solid media",

author = "Е.А. Попова and Бойцов, {Виталий Михайлович} and Степаков, {Александр Владимирович}",

year = "2024",

month = jun,

day = "1",

doi = "10.1134/S1070363224060057",

language = "English",

volume = "94",

pages = "1251–1256",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "6",

}

RIS

TY - JOUR

T1 - [4+2] Dimerization of Arylmaleic Acids Imides on Solid Media

AU - Попова, Е.А.

AU - Бойцов, Виталий Михайлович

AU - Степаков, Александр Владимирович

PY - 2024/6/1

Y1 - 2024/6/1

N2 - Abstract: The [4+2] dimerization of arylmaleic acid imides, which occurs in the presence of 3,5-dimethyl-1H-pyrazole on solid media under convection or microwave heating, has been studied. It was shown that dimerization proceeds stereoselectively with the formation of polycyclic compounds with a decahydrobenzo[e]pyrrolo[3,4-g]isoindole skeleton, predominantly of the endo-configuration. The best results in yields and stereoselectivity were achieved when reactions were carried out on silica gel under microwave activation conditions.

AB - Abstract: The [4+2] dimerization of arylmaleic acid imides, which occurs in the presence of 3,5-dimethyl-1H-pyrazole on solid media under convection or microwave heating, has been studied. It was shown that dimerization proceeds stereoselectively with the formation of polycyclic compounds with a decahydrobenzo[e]pyrrolo[3,4-g]isoindole skeleton, predominantly of the endo-configuration. The best results in yields and stereoselectivity were achieved when reactions were carried out on silica gel under microwave activation conditions.

KW - 3,5-dimethyl-1H-pyrazole

KW - [4+2] dimerization

KW - arylmaleic acid imides

KW - polycyclic compounds

KW - reactions on solid media

UR - https://www.mendeley.com/catalogue/cb6821d3-4f93-3fd1-9564-40530bba8295/

U2 - 10.1134/S1070363224060057

DO - 10.1134/S1070363224060057

M3 - Article

VL - 94

SP - 1251

EP - 1256

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 6

ER -

ID: 127224949