2-Chlorobenzoate Complex of Cu(II) › SPbU Researchers Portal

2-Chlorobenzoate Complex of Cu(II): Unexpected Appearance of Halogen center dot center dot center dot Halogen Contacts in Solid State

Research output: Contribution to journal › Article › peer-review

Institute of Chemistry

DOI

https://doi.org/10.1007/s10876-019-01574-z
Final published version

Sergey A. Adonin
Mikhail D. Petrov
Alexander S. Novikov
Rishat R. Shiriyazdanov
Maxim N. Sokolov
Vladimir P. Fedin

Complex of copper [Cu-2(2-ClBenz)(4)((acetone)(2)] (2-ClBenz=2-chlorobenzoate) was prepared and characterized by X-ray diffractometry. In the crystal structure, the binuclear complex fragments are connected via ClCl contacts (3.440 angstrom); their energies were estimated by theoretical methods.

Original language	English
Pages (from-to)	857-861
Number of pages	5
Journal	Journal of Cluster Science
Volume	30
Issue number	4
DOIs	https://doi.org/10.1007/s10876-019-01574-z
State	Published - 15 Jul 2019

Scopus subject areas

Condensed Matter Physics
Chemistry(all)
Materials Science(all)
Biochemistry

Research areas

Carboxylate complexes, Copper, Crystal structure, Halogen bonding, Supramolecular contacts, CARBOXYLATE BRIDGES, S-ALKYL DERIVATIVES, MOLECULAR-STRUCTURE, BINUCLEAR COPPER(II) COMPLEXES, PYRIDINE, X-RAY-STRUCTURE, ACID. CRYSTAL-STRUCTURE, COORDINATION POLYMERS, METAL-IONS, BOND

ID: 41855819