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1,3-Dipolar cycloaddition reactions of ketene imine ylides derived from dichlorocarbene and diphenylketene imines. / Novikov, M. S.; Khlebnikov, A. F.; Kostikov, R. R.

In: Russian Journal of Organic Chemistry, Vol. 32, No. 5, 01.05.1996, p. 637-644.

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@article{70e065bc33254c53a655559be2334de6,
title = "1,3-Dipolar cycloaddition reactions of ketene imine ylides derived from dichlorocarbene and diphenylketene imines",
abstract = "Ketene imine ylides, generated from dichlorocarbene and diphenylketene alkyl- and arylimines undergo selective 1,3-dipolar cycloaddition to ethyl acrylate, methyl methacrylate, and acrylonitrile to give pyrrole and/or pyridine derivatives. The latter are formed by dichlorocyclopropanation of intermediate 2-chloropyrrolidones. A new type of transformation of ketene imine ylides to azomethine ylides was discovered in the reaction with methyl methacrylate.",
author = "Novikov, {M. S.} and Khlebnikov, {A. F.} and Kostikov, {R. R.}",
year = "1996",
month = may,
day = "1",
language = "English",
volume = "32",
pages = "637--644",
journal = "Russian Journal of Organic Chemistry",
issn = "1070-4280",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "5",

}

RIS

TY - JOUR

T1 - 1,3-Dipolar cycloaddition reactions of ketene imine ylides derived from dichlorocarbene and diphenylketene imines

AU - Novikov, M. S.

AU - Khlebnikov, A. F.

AU - Kostikov, R. R.

PY - 1996/5/1

Y1 - 1996/5/1

N2 - Ketene imine ylides, generated from dichlorocarbene and diphenylketene alkyl- and arylimines undergo selective 1,3-dipolar cycloaddition to ethyl acrylate, methyl methacrylate, and acrylonitrile to give pyrrole and/or pyridine derivatives. The latter are formed by dichlorocyclopropanation of intermediate 2-chloropyrrolidones. A new type of transformation of ketene imine ylides to azomethine ylides was discovered in the reaction with methyl methacrylate.

AB - Ketene imine ylides, generated from dichlorocarbene and diphenylketene alkyl- and arylimines undergo selective 1,3-dipolar cycloaddition to ethyl acrylate, methyl methacrylate, and acrylonitrile to give pyrrole and/or pyridine derivatives. The latter are formed by dichlorocyclopropanation of intermediate 2-chloropyrrolidones. A new type of transformation of ketene imine ylides to azomethine ylides was discovered in the reaction with methyl methacrylate.

UR - http://www.scopus.com/inward/record.url?scp=21544463028&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:21544463028

VL - 32

SP - 637

EP - 644

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 5

ER -

ID: 28246248