Standard

1,2,4-Triazines and Calcium Carbide in Catalyst-Free Synthesis of 2,3,6-Trisubstituted Pyridines and Their D-, 13C-, and Doubly D2-13C2-Labeled Analogues. / Воронин, Владимир Владимирович; Полынский, Михаил Вячеславович; Ледовская, Мария Сергеевна.

In: Chemistry - An Asian Journal, Vol. 18, No. 23, e202300781, 01.12.2023.

Research output: Contribution to journal › Article › peer-review

Harvard

Воронин, ВВ, Полынский, МВ & Ледовская, МС 2023, '1,2,4-Triazines and Calcium Carbide in Catalyst-Free Synthesis of 2,3,6-Trisubstituted Pyridines and Their D-, 13C-, and Doubly D2-13C2-Labeled Analogues', Chemistry - An Asian Journal, vol. 18, no. 23, e202300781. https://doi.org/10.1002/asia.202300781

APA

Воронин, В. В., Полынский, М. В., & Ледовская, М. С. (2023). 1,2,4-Triazines and Calcium Carbide in Catalyst-Free Synthesis of 2,3,6-Trisubstituted Pyridines and Their D-, 13C-, and Doubly D2-13C2-Labeled Analogues. Chemistry - An Asian Journal, 18(23), [e202300781]. https://doi.org/10.1002/asia.202300781

Vancouver

Воронин ВВ, Полынский МВ, Ледовская МС. 1,2,4-Triazines and Calcium Carbide in Catalyst-Free Synthesis of 2,3,6-Trisubstituted Pyridines and Their D-, 13C-, and Doubly D2-13C2-Labeled Analogues. Chemistry - An Asian Journal. 2023 Dec 1;18(23). e202300781. https://doi.org/10.1002/asia.202300781

Author

Воронин, Владимир Владимирович ; Полынский, Михаил Вячеславович ; Ледовская, Мария Сергеевна. / 1,2,4-Triazines and Calcium Carbide in Catalyst-Free Synthesis of 2,3,6-Trisubstituted Pyridines and Their D-, 13C-, and Doubly D2-13C2-Labeled Analogues. In: Chemistry - An Asian Journal. 2023 ; Vol. 18, No. 23.

BibTeX

@article{61d8865c82cf417d8ac45ab2ef14d40b,
title = "1,2,4-Triazines and Calcium Carbide in Catalyst-Free Synthesis of 2,3,6-Trisubstituted Pyridines and Their D-, 13C-, and Doubly D2-13C2-Labeled Analogues",
abstract = "A novel synthetic approach to 2,3,6-trisubstituted pyridines, their 4,5-dideuterated derivatives, 4,5-13C2- and doubly-labeled D2‑13C2-pyridines has been developed using catalyst-free [4+2] cycloaddition of 1,2,4-triazines and in situ generated acetylene or labeled acetylene. Calcium carbide and water or deuterium oxide were used for the in situ generation of acetylene and dideuteroacetylene. Calcium carbide-13C2 in the mixture with water or deuterium oxide was applied as 13C2-acetylene and D2-13C2-acetylene source.",
keywords = "ацетилен, карбид кальция, пиридин, реакция Дильса-Альдера, alkynes, carbides, cycloaddition, isotopic labeling, nitrogen heterocycles",
author = "Воронин, {Владимир Владимирович} and Полынский, {Михаил Вячеславович} and Ледовская, {Мария Сергеевна}",
year = "2023",
month = dec,
day = "1",
doi = "10.1002/asia.202300781",
language = "English",
volume = "18",
journal = "Chemistry - An Asian Journal",
issn = "1861-4728",
publisher = "Wiley-Blackwell",
number = "23",

}

RIS

TY - JOUR

T1 - 1,2,4-Triazines and Calcium Carbide in Catalyst-Free Synthesis of 2,3,6-Trisubstituted Pyridines and Their D-, 13C-, and Doubly D2-13C2-Labeled Analogues

AU - Воронин, Владимир Владимирович

AU - Полынский, Михаил Вячеславович

AU - Ледовская, Мария Сергеевна

PY - 2023/12/1

Y1 - 2023/12/1

N2 - A novel synthetic approach to 2,3,6-trisubstituted pyridines, their 4,5-dideuterated derivatives, 4,5-13C2- and doubly-labeled D2‑13C2-pyridines has been developed using catalyst-free [4+2] cycloaddition of 1,2,4-triazines and in situ generated acetylene or labeled acetylene. Calcium carbide and water or deuterium oxide were used for the in situ generation of acetylene and dideuteroacetylene. Calcium carbide-13C2 in the mixture with water or deuterium oxide was applied as 13C2-acetylene and D2-13C2-acetylene source.

AB - A novel synthetic approach to 2,3,6-trisubstituted pyridines, their 4,5-dideuterated derivatives, 4,5-13C2- and doubly-labeled D2‑13C2-pyridines has been developed using catalyst-free [4+2] cycloaddition of 1,2,4-triazines and in situ generated acetylene or labeled acetylene. Calcium carbide and water or deuterium oxide were used for the in situ generation of acetylene and dideuteroacetylene. Calcium carbide-13C2 in the mixture with water or deuterium oxide was applied as 13C2-acetylene and D2-13C2-acetylene source.

KW - ацетилен

KW - карбид кальция

KW - пиридин

KW - реакция Дильса-Альдера

KW - alkynes

KW - carbides

KW - cycloaddition

KW - isotopic labeling

KW - nitrogen heterocycles

UR - https://www.mendeley.com/catalogue/27eae0c8-016d-3cb3-ba78-20c0a57c8d29/

U2 - 10.1002/asia.202300781

DO - 10.1002/asia.202300781

M3 - Article

VL - 18

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

SN - 1861-4728

IS - 23

M1 - e202300781

ER -

ID: 113569274