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ВЫСОКОТЕМПЕРАТУРНОЕ ПОВЕДЕНИЕ СОЕДИНЕНИЯ CuMo3O10 · H2O. / Ismagilova, R. M.; Zhitova, E. S.; Zolotarev, A. A.; Shilovskikh, V. V.

In: Zapiski Rossiiskogo Mineralogicheskogo Obshchestva, Vol. 150, No. 2, 2021, p. 92-105.

Research output: Contribution to journal › Article › peer-review

Harvard

Ismagilova, RM, Zhitova, ES, Zolotarev, AA & Shilovskikh, VV 2021, 'ВЫСОКОТЕМПЕРАТУРНОЕ ПОВЕДЕНИЕ СОЕДИНЕНИЯ CuMo3O10 · H2O', Zapiski Rossiiskogo Mineralogicheskogo Obshchestva, vol. 150, no. 2, pp. 92-105. https://doi.org/10.31857/S0869605521020076

APA

Ismagilova, R. M., Zhitova, E. S., Zolotarev, A. A., & Shilovskikh, V. V. (2021). ВЫСОКОТЕМПЕРАТУРНОЕ ПОВЕДЕНИЕ СОЕДИНЕНИЯ CuMo3O10 · H2O. Zapiski Rossiiskogo Mineralogicheskogo Obshchestva, 150(2), 92-105. https://doi.org/10.31857/S0869605521020076

Vancouver

Ismagilova RM, Zhitova ES, Zolotarev AA, Shilovskikh VV. ВЫСОКОТЕМПЕРАТУРНОЕ ПОВЕДЕНИЕ СОЕДИНЕНИЯ CuMo3O10 · H2O. Zapiski Rossiiskogo Mineralogicheskogo Obshchestva. 2021;150(2):92-105. https://doi.org/10.31857/S0869605521020076

Author

Ismagilova, R. M. ; Zhitova, E. S. ; Zolotarev, A. A. ; Shilovskikh, V. V. / ВЫСОКОТЕМПЕРАТУРНОЕ ПОВЕДЕНИЕ СОЕДИНЕНИЯ CuMo3O10 · H2O. In: Zapiski Rossiiskogo Mineralogicheskogo Obshchestva. 2021 ; Vol. 150, No. 2. pp. 92-105.

BibTeX

@article{318faa3e763046fd99469257a984ce69,
title = "ВЫСОКОТЕМПЕРАТУРНОЕ ПОВЕДЕНИЕ СОЕДИНЕНИЯ CuMo3O10 · H2O",
abstract = "CuMo3O10 · H2O crystals have been obtained by hydrothermal synthesis as a result of reaction between (NH4)6Mo7O24 · 4H2O and Cu(CH3COO)2 at 220 °C during 7 days. The X-ray powder diffraction data in wide range of temperature have shown that the studied phase is stable within the range from –180 to 300 °С. Its thermal expansion is anisotropic, thermal expansion coefficients, calculated at Т = 100 °С, are: αa = 28.5, αb = 6.1 and αc = 13.3 °С–1. Structural changes have been analyzed by the structure refinement method based on the single-crystal X-ray diffraction data at different temperatures. Thermal expansion anisotropy is connected with the chain-structure type and the angle deformations caused by changes in inter-atomic angles in the CuO6 octahedra and in inter-polyhedral angles between copper octahedron and trimolybdate chains. The high-temperature behavior of CuMo3O10 · H2O is compared in the paper with behavior of chemically close copper molybdates – lindgrenite, szenicsite and cupromolybdate.",
keywords = "Copper and molybdenum compounds, Dynamics of crystal structure, Thermal expansion, Trimolybdates",
author = "Ismagilova, {R. M.} and Zhitova, {E. S.} and Zolotarev, {A. A.} and Shilovskikh, {V. V.}",
note = "Publisher Copyright: {\textcopyright} 2021 Eco-Vector LLC. All rights reserved.",
year = "2021",
doi = "10.31857/S0869605521020076",
language = "русский",
volume = "150",
pages = "92--105",
journal = "ЗАПИСКИ РОССИЙСКОГО МИНЕРАЛОГИЧЕСКОГО ОБЩЕСТВА",
issn = "0869-6055",
publisher = "Издательство {"}Наука{"}",
number = "2",

}

RIS

TY - JOUR

T1 - ВЫСОКОТЕМПЕРАТУРНОЕ ПОВЕДЕНИЕ СОЕДИНЕНИЯ CuMo3O10 · H2O

AU - Ismagilova, R. M.

AU - Zhitova, E. S.

AU - Zolotarev, A. A.

AU - Shilovskikh, V. V.

N1 - Publisher Copyright: © 2021 Eco-Vector LLC. All rights reserved.

PY - 2021

Y1 - 2021

N2 - CuMo3O10 · H2O crystals have been obtained by hydrothermal synthesis as a result of reaction between (NH4)6Mo7O24 · 4H2O and Cu(CH3COO)2 at 220 °C during 7 days. The X-ray powder diffraction data in wide range of temperature have shown that the studied phase is stable within the range from –180 to 300 °С. Its thermal expansion is anisotropic, thermal expansion coefficients, calculated at Т = 100 °С, are: αa = 28.5, αb = 6.1 and αc = 13.3 °С–1. Structural changes have been analyzed by the structure refinement method based on the single-crystal X-ray diffraction data at different temperatures. Thermal expansion anisotropy is connected with the chain-structure type and the angle deformations caused by changes in inter-atomic angles in the CuO6 octahedra and in inter-polyhedral angles between copper octahedron and trimolybdate chains. The high-temperature behavior of CuMo3O10 · H2O is compared in the paper with behavior of chemically close copper molybdates – lindgrenite, szenicsite and cupromolybdate.

AB - CuMo3O10 · H2O crystals have been obtained by hydrothermal synthesis as a result of reaction between (NH4)6Mo7O24 · 4H2O and Cu(CH3COO)2 at 220 °C during 7 days. The X-ray powder diffraction data in wide range of temperature have shown that the studied phase is stable within the range from –180 to 300 °С. Its thermal expansion is anisotropic, thermal expansion coefficients, calculated at Т = 100 °С, are: αa = 28.5, αb = 6.1 and αc = 13.3 °С–1. Structural changes have been analyzed by the structure refinement method based on the single-crystal X-ray diffraction data at different temperatures. Thermal expansion anisotropy is connected with the chain-structure type and the angle deformations caused by changes in inter-atomic angles in the CuO6 octahedra and in inter-polyhedral angles between copper octahedron and trimolybdate chains. The high-temperature behavior of CuMo3O10 · H2O is compared in the paper with behavior of chemically close copper molybdates – lindgrenite, szenicsite and cupromolybdate.

KW - Copper and molybdenum compounds

KW - Dynamics of crystal structure

KW - Thermal expansion

KW - Trimolybdates

UR - http://www.scopus.com/inward/record.url?scp=85120048588&partnerID=8YFLogxK

U2 - 10.31857/S0869605521020076

DO - 10.31857/S0869605521020076

M3 - статья

AN - SCOPUS:85120048588

VL - 150

SP - 92

EP - 105

JO - ЗАПИСКИ РОССИЙСКОГО МИНЕРАЛОГИЧЕСКОГО ОБЩЕСТВА

JF - ЗАПИСКИ РОССИЙСКОГО МИНЕРАЛОГИЧЕСКОГО ОБЩЕСТВА

SN - 0869-6055

IS - 2

ER -

ID: 99016664