Research output: Contribution to journal › Article › peer-review
The preference of empirical methodology evaluation of thermochemical data of organic, heteroorganic and inorganic molecules and intermediate species against quantum chemical approach is shown. The problems of enthalpy sublimation definition and bond dissociation energy from kinetical data of bimolecular reactions and ion formation enthalpy by photoionization mass-spectroscopy data are considered.
Original language | Russian |
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Pages (from-to) | 104-119 |
Journal | ВЕСТНИК САНКТ-ПЕТЕРБУРГСКОГО УНИВЕРСИТЕТА. СЕРИЯ 4: ФИЗИКА, ХИМИЯ |
Issue number | 2 |
State | Published - 2009 |
ID: 5284796