Trifluoromethanesulfonic acid in organic synthesis

A. N. Kazakova, A. V. Vasilyev

Результат исследований: Научные публикации в периодических изданияхОбзорная статья

10 Цитирования (Scopus)

Выдержка

The review analyzes data published in the past decade on the use of trifluoromethanesulfonic acid (triflic acid, CF3SO3H, TfOH) in organic synthesis, in particular in electrophilic aromatic substitution (Friedel–Crafts) reactions, formation of carbon–carbon and carbon–heteroatom bonds, isomerizations, syntheses of carboand heterocyclic structures, and other reactions, as well as in natural and organometallic compounds chemistry. The high protonating power and low nucleophilicity makes trifluoromethanesulfonic acid capable of generating from organic molecules cationic species which can be detected by spectral methods (NMR, IR spectroscopy, etc.), and their transformations can be studied. Experimental simplicity and efficiency of reactions promoted by trifluoromethanesulfonic acid make it a convenient reagent for the synthesis of new organic compounds.

Язык оригиналаанглийский
Страницы (с-по)485-509
Число страниц25
ЖурналRussian Journal of Organic Chemistry
Том53
Номер выпуска4
DOI
СостояниеОпубликовано - 1 янв 2017

Отпечаток

Organometallic Compounds
Isomerization
Organic compounds
Infrared spectroscopy
Substitution reactions
Nuclear magnetic resonance
Molecules
trifluoromethanesulfonic acid

Предметные области Scopus

  • Органическая химия

Цитировать

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Trifluoromethanesulfonic acid in organic synthesis. / Kazakova, A. N.; Vasilyev, A. V.

В: Russian Journal of Organic Chemistry, Том 53, № 4, 01.01.2017, стр. 485-509.

Результат исследований: Научные публикации в периодических изданияхОбзорная статья

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