Выдержка
The review analyzes data published in the past decade on the use of trifluoromethanesulfonic acid (triflic acid, CF3SO3H, TfOH) in organic synthesis, in particular in electrophilic aromatic substitution (Friedel–Crafts) reactions, formation of carbon–carbon and carbon–heteroatom bonds, isomerizations, syntheses of carboand heterocyclic structures, and other reactions, as well as in natural and organometallic compounds chemistry. The high protonating power and low nucleophilicity makes trifluoromethanesulfonic acid capable of generating from organic molecules cationic species which can be detected by spectral methods (NMR, IR spectroscopy, etc.), and their transformations can be studied. Experimental simplicity and efficiency of reactions promoted by trifluoromethanesulfonic acid make it a convenient reagent for the synthesis of new organic compounds.
| Язык оригинала | английский |
|---|---|
| Страницы (с-по) | 485-509 |
| Число страниц | 25 |
| Журнал | Russian Journal of Organic Chemistry |
| Том | 53 |
| Номер выпуска | 4 |
| DOI | |
| Состояние | Опубликовано - 1 янв 2017 |
Отпечаток
Предметные области Scopus
- Органическая химия
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Trifluoromethanesulfonic acid in organic synthesis. / Kazakova, A. N.; Vasilyev, A. V.
В: Russian Journal of Organic Chemistry, Том 53, № 4, 01.01.2017, стр. 485-509.Результат исследований: Научные публикации в периодических изданиях › Обзорная статья
TY - JOUR
T1 - Trifluoromethanesulfonic acid in organic synthesis
AU - Kazakova, A. N.
AU - Vasilyev, A. V.
PY - 2017/1/1
Y1 - 2017/1/1
N2 - The review analyzes data published in the past decade on the use of trifluoromethanesulfonic acid (triflic acid, CF3SO3H, TfOH) in organic synthesis, in particular in electrophilic aromatic substitution (Friedel–Crafts) reactions, formation of carbon–carbon and carbon–heteroatom bonds, isomerizations, syntheses of carboand heterocyclic structures, and other reactions, as well as in natural and organometallic compounds chemistry. The high protonating power and low nucleophilicity makes trifluoromethanesulfonic acid capable of generating from organic molecules cationic species which can be detected by spectral methods (NMR, IR spectroscopy, etc.), and their transformations can be studied. Experimental simplicity and efficiency of reactions promoted by trifluoromethanesulfonic acid make it a convenient reagent for the synthesis of new organic compounds.
AB - The review analyzes data published in the past decade on the use of trifluoromethanesulfonic acid (triflic acid, CF3SO3H, TfOH) in organic synthesis, in particular in electrophilic aromatic substitution (Friedel–Crafts) reactions, formation of carbon–carbon and carbon–heteroatom bonds, isomerizations, syntheses of carboand heterocyclic structures, and other reactions, as well as in natural and organometallic compounds chemistry. The high protonating power and low nucleophilicity makes trifluoromethanesulfonic acid capable of generating from organic molecules cationic species which can be detected by spectral methods (NMR, IR spectroscopy, etc.), and their transformations can be studied. Experimental simplicity and efficiency of reactions promoted by trifluoromethanesulfonic acid make it a convenient reagent for the synthesis of new organic compounds.
UR - http://www.scopus.com/inward/record.url?scp=85019989986&partnerID=8YFLogxK
U2 - 10.1134/S1070428017040017
DO - 10.1134/S1070428017040017
M3 - Review article
AN - SCOPUS:85019989986
VL - 53
SP - 485
EP - 509
JO - Russian Journal of Organic Chemistry
JF - Russian Journal of Organic Chemistry
SN - 1070-4280
IS - 4
ER -