Thermal expansion and polymorphism in a series of rubidium cesium boroleucites

M. G. Krzhizhanovskaya, R. S. Bubnova, V. L. Ugolkov, S. K. Filatov

Результат исследований: Научные публикации в периодических изданияхстатья

7 Цитирования (Scopus)

Выдержка

The crystal structure of the boroleucite solid solution Rb 0.40Cs0.54B0.94Si2.06O6 is refined in space group I-43d by the Rietveld method with the use of the X-ray powder diffraction data. The refinement data complement the available crystal chemical characteristics of Rb1-x Cs x BSi 2O6 solid solutions. The thermal expansion and phase transformations of Rb1-x Cs x BSi2O6 borosilicates are investigated in parallel by high-temperature X-ray diffraction with conventional powdered samples and by the dilatometric method with samples in the form of pressed pellets. It is demonstrated that the thermal expansion coefficients, as well as the temperatures and sequence of polymorphic transitions, which are determined from the data obtained by two methods are in close agreement. The temperature curve of the I-43d ⇄ Ia3d phase transition for the Rb1-x Cs x BSi2O6 solid solution system is constructed from the data obtained by both methods. It is shown with the use of the structural data obtained by the Rietveld method that, at temperatures above 800°C, rubidium-cesium boroleucites undergo decomposition due to the release of alkali cations.

Язык оригиналаанглийский
Страницы (с-по)242-249
Число страниц8
ЖурналGlass Physics and Chemistry
Том33
Номер выпуска3
DOI
СостояниеОпубликовано - 1 июн 2007

Отпечаток

Rubidium
Cesium
polymorphism
rubidium
Polymorphism
cesium
Thermal expansion
thermal expansion
solid solutions
Rietveld method
Solid solutions
Phase transitions
diffraction
pellets
complement
Temperature
phase transformations
temperature
alkalies
Alkalies

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  • Керамика и композитные материалы

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abstract = "The crystal structure of the boroleucite solid solution Rb 0.40Cs0.54B0.94Si2.06O6 is refined in space group I-43d by the Rietveld method with the use of the X-ray powder diffraction data. The refinement data complement the available crystal chemical characteristics of Rb1-x Cs x BSi 2O6 solid solutions. The thermal expansion and phase transformations of Rb1-x Cs x BSi2O6 borosilicates are investigated in parallel by high-temperature X-ray diffraction with conventional powdered samples and by the dilatometric method with samples in the form of pressed pellets. It is demonstrated that the thermal expansion coefficients, as well as the temperatures and sequence of polymorphic transitions, which are determined from the data obtained by two methods are in close agreement. The temperature curve of the I-43d ⇄ Ia3d phase transition for the Rb1-x Cs x BSi2O6 solid solution system is constructed from the data obtained by both methods. It is shown with the use of the structural data obtained by the Rietveld method that, at temperatures above 800°C, rubidium-cesium boroleucites undergo decomposition due to the release of alkali cations.",
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Thermal expansion and polymorphism in a series of rubidium cesium boroleucites. / Krzhizhanovskaya, M. G.; Bubnova, R. S.; Ugolkov, V. L.; Filatov, S. K.

В: Glass Physics and Chemistry, Том 33, № 3, 01.06.2007, стр. 242-249.

Результат исследований: Научные публикации в периодических изданияхстатья

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AU - Bubnova, R. S.

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AU - Filatov, S. K.

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AB - The crystal structure of the boroleucite solid solution Rb 0.40Cs0.54B0.94Si2.06O6 is refined in space group I-43d by the Rietveld method with the use of the X-ray powder diffraction data. The refinement data complement the available crystal chemical characteristics of Rb1-x Cs x BSi 2O6 solid solutions. The thermal expansion and phase transformations of Rb1-x Cs x BSi2O6 borosilicates are investigated in parallel by high-temperature X-ray diffraction with conventional powdered samples and by the dilatometric method with samples in the form of pressed pellets. It is demonstrated that the thermal expansion coefficients, as well as the temperatures and sequence of polymorphic transitions, which are determined from the data obtained by two methods are in close agreement. The temperature curve of the I-43d ⇄ Ia3d phase transition for the Rb1-x Cs x BSi2O6 solid solution system is constructed from the data obtained by both methods. It is shown with the use of the structural data obtained by the Rietveld method that, at temperatures above 800°C, rubidium-cesium boroleucites undergo decomposition due to the release of alkali cations.

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