The temperature dependence of the coordination numbers of some monatomic ions in aqueous solutions of electrolytes

Результат исследований: Научные публикации в периодических изданияхстатья

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Аннотация

The structure of hydration shells was studied for the ionic constituents of NaBr, NaNO3, and NaCl. The thermal stability of the nearest environment of the Na+ cation was estimated by measuring the relaxation rates of deuterium nuclei in NaNO3-D2O solutions. A hypothesis was suggested according to which changes in the hydration of Cl- anions influenced the amount of "free" water and the occurrence of energy reactions in it. Copyright © 2005 by Pleiades Publishing, Inc.
Язык оригиналаанглийский
Страницы (с-по)893-897
ЖурналRussian Journal of Physical Chemistry A
Том79
Номер выпуска6
СостояниеОпубликовано - 2005
Опубликовано для внешнего пользованияДа

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