Abstract: Solutions of tetraethylammonium and lithium chlorides in acetonitrile were studied by electronic absorption spectroscopy. It was shown that at concentrations up to 100 mmol/L tetraethylammonium chloride completely dissociates. The association constant of lithium chloride in acetonitrile (Kass = 4800 mol–1 L) was determined by the spectrophotometric method. The electronic absorption spectra of the Li+Cl– ionic pair and Cl– anion in acetonitrile were studied.
Предметные области Scopus
- Химия (все)