Standard formation enthalpies of gas phase molecular complexes derived by taking into account the heat capacity difference of the gas phase dissociation processes: Experimental tensimetry data revisited

E.I. Davydova, Yu.V. Kondrat’ev, A.S. Lisovenko, A.V. Pomogaeva, T.N. Sevastianova, A.Y. Timoshkin

Результат исследований: Научные публикации в периодических изданияхстатья

Аннотация

High temperature tensimetry data on homogeneous gas phase dissociation of donor-acceptor complexes of group 13–15 metal halides have been analyzed. Thermodynamic characteristics and heat capacities have been computed by DFT methods. Standard dissociation enthalpies and standard formation enthalpies of gaseous donor-acceptor complexes have been obtained by combination of experimental and computational data with accounting for the heat capacity change.
Язык оригиналаанглийский
Номер статьи178571
ЖурналThermochimica Acta
Том686
Ранняя дата в режиме онлайн28 фев 2020
СостояниеОпубликовано - 2020

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