Spectroscopic and theoretical studies of potassium sodium l-(+)-tartrate tetrahydrate and l-tartaric acid used as precursors for in situ laser-induced deposition of the catalytically active copper microstructures

Ilya I. Tumkin, Evgeniia M. Khairullina, Liubov A. Myund, Lev S. Logunov, Dmitrii I. Gordeychuk, Maxim S. Panov, Vladimir A. Kochemirovsky

Результат исследований: Научные публикации в периодических изданияхстатьянаучнаярецензирование

Выдержка

In this work we study the influence of l-(+)-?NaC(4)H(4)O(6)x4H(2)O (KNaT) and l-H2C4H4O6 (H2T) on the complexation processes occurring during in situ laser-induced catalytic destruction of the organic components of the aqueous solutions with formation of the unsaturated hydrocarbons. For that purpose, ATR-FTIR, Raman, IR, and NIR spectroscopy as well as quantum chemical calculations were implemented. It was observed that hydration of T2- anion via carboxylate groups is stronger than that via hydroxyl groups. We also established the changes in the spectral characteristics of the absorption bands corresponding to vibrations of T2-, HT-, and H2T, at solid state-liquid and acid-salt transitions, depending on concentration of the solution components and the [OH-]/[H2T] ratio. Finally, it was shown that ethylene is a main product of the catalytic destruction of the copper tartrate complexes.

Язык оригиналаанглийский
Номер статьи89
Число страниц11
ЖурналOptical and Quantum Electronics
Том51
Номер выпуска3
DOI
СостояниеОпубликовано - 1 мар 2019

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    Предметные области Scopus

    • Электроника, оптика и магнитные материалы
    • Атомная и молекулярная физика и оптика
    • Электротехника и электроника

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    title = "Spectroscopic and theoretical studies of potassium sodium l-(+)-tartrate tetrahydrate and l-tartaric acid used as precursors for in situ laser-induced deposition of the catalytically active copper microstructures",
    abstract = "In this work we study the influence of l-(+)-?NaC(4)H(4)O(6)x4H(2)O (KNaT) and l-H2C4H4O6 (H2T) on the complexation processes occurring during in situ laser-induced catalytic destruction of the organic components of the aqueous solutions with formation of the unsaturated hydrocarbons. For that purpose, ATR-FTIR, Raman, IR, and NIR spectroscopy as well as quantum chemical calculations were implemented. It was observed that hydration of T2- anion via carboxylate groups is stronger than that via hydroxyl groups. We also established the changes in the spectral characteristics of the absorption bands corresponding to vibrations of T2-, HT-, and H2T, at solid state-liquid and acid-salt transitions, depending on concentration of the solution components and the [OH-]/[H2T] ratio. Finally, it was shown that ethylene is a main product of the catalytic destruction of the copper tartrate complexes.",
    keywords = "ATR-FTIR, Catalysis, DFT calculations, IR, Laser-induced copper deposition, NIR, Raman spectroscopy, Sodium potassium tartrate tetrahydrate, Tartaric acid, TARTRATE, GLYCEROL, RAMAN, GROWTH, LIGAND",
    author = "Tumkin, {Ilya I.} and Khairullina, {Evgeniia M.} and Myund, {Liubov A.} and Logunov, {Lev S.} and Gordeychuk, {Dmitrii I.} and Panov, {Maxim S.} and Kochemirovsky, {Vladimir A.}",
    year = "2019",
    month = "3",
    day = "1",
    doi = "10.1007/s11082-019-1800-5",
    language = "English",
    volume = "51",
    journal = "Optical and Quantum Electronics",
    issn = "0306-8919",
    publisher = "Springer",
    number = "3",

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    Spectroscopic and theoretical studies of potassium sodium l-(+)-tartrate tetrahydrate and l-tartaric acid used as precursors for in situ laser-induced deposition of the catalytically active copper microstructures. / Tumkin, Ilya I.; Khairullina, Evgeniia M.; Myund, Liubov A.; Logunov, Lev S.; Gordeychuk, Dmitrii I.; Panov, Maxim S.; Kochemirovsky, Vladimir A.

    В: Optical and Quantum Electronics, Том 51, № 3, 89, 01.03.2019.

    Результат исследований: Научные публикации в периодических изданияхстатьянаучнаярецензирование

    TY - JOUR

    T1 - Spectroscopic and theoretical studies of potassium sodium l-(+)-tartrate tetrahydrate and l-tartaric acid used as precursors for in situ laser-induced deposition of the catalytically active copper microstructures

    AU - Tumkin, Ilya I.

    AU - Khairullina, Evgeniia M.

    AU - Myund, Liubov A.

    AU - Logunov, Lev S.

    AU - Gordeychuk, Dmitrii I.

    AU - Panov, Maxim S.

    AU - Kochemirovsky, Vladimir A.

    PY - 2019/3/1

    Y1 - 2019/3/1

    N2 - In this work we study the influence of l-(+)-?NaC(4)H(4)O(6)x4H(2)O (KNaT) and l-H2C4H4O6 (H2T) on the complexation processes occurring during in situ laser-induced catalytic destruction of the organic components of the aqueous solutions with formation of the unsaturated hydrocarbons. For that purpose, ATR-FTIR, Raman, IR, and NIR spectroscopy as well as quantum chemical calculations were implemented. It was observed that hydration of T2- anion via carboxylate groups is stronger than that via hydroxyl groups. We also established the changes in the spectral characteristics of the absorption bands corresponding to vibrations of T2-, HT-, and H2T, at solid state-liquid and acid-salt transitions, depending on concentration of the solution components and the [OH-]/[H2T] ratio. Finally, it was shown that ethylene is a main product of the catalytic destruction of the copper tartrate complexes.

    AB - In this work we study the influence of l-(+)-?NaC(4)H(4)O(6)x4H(2)O (KNaT) and l-H2C4H4O6 (H2T) on the complexation processes occurring during in situ laser-induced catalytic destruction of the organic components of the aqueous solutions with formation of the unsaturated hydrocarbons. For that purpose, ATR-FTIR, Raman, IR, and NIR spectroscopy as well as quantum chemical calculations were implemented. It was observed that hydration of T2- anion via carboxylate groups is stronger than that via hydroxyl groups. We also established the changes in the spectral characteristics of the absorption bands corresponding to vibrations of T2-, HT-, and H2T, at solid state-liquid and acid-salt transitions, depending on concentration of the solution components and the [OH-]/[H2T] ratio. Finally, it was shown that ethylene is a main product of the catalytic destruction of the copper tartrate complexes.

    KW - ATR-FTIR

    KW - Catalysis

    KW - DFT calculations

    KW - IR

    KW - Laser-induced copper deposition

    KW - NIR

    KW - Raman spectroscopy

    KW - Sodium potassium tartrate tetrahydrate

    KW - Tartaric acid

    KW - TARTRATE

    KW - GLYCEROL

    KW - RAMAN

    KW - GROWTH

    KW - LIGAND

    UR - http://www.scopus.com/inward/record.url?scp=85063025904&partnerID=8YFLogxK

    U2 - 10.1007/s11082-019-1800-5

    DO - 10.1007/s11082-019-1800-5

    M3 - Article

    VL - 51

    JO - Optical and Quantum Electronics

    JF - Optical and Quantum Electronics

    SN - 0306-8919

    IS - 3

    M1 - 89

    ER -