Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Spectral Lineshape Parameters Revisited for HF in a Bath of Argon I. Widths and Shifts in the (0-0), (0-1), and (0-2) Bands. / Grigoriev, I. M.; Le Doucen, R.; Boissoles, J.; Calil, B.; Boulet, C.; Hartmann, J. M.; Bruet, X.; Dubernet, M. L.
в: Journal of Molecular Spectroscopy, Том 198, № 2, 01.01.1999, стр. 249-256.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Spectral Lineshape Parameters Revisited for HF in a Bath of Argon I. Widths and Shifts in the (0-0), (0-1), and (0-2) Bands
AU - Grigoriev, I. M.
AU - Le Doucen, R.
AU - Boissoles, J.
AU - Calil, B.
AU - Boulet, C.
AU - Hartmann, J. M.
AU - Bruet, X.
AU - Dubernet, M. L.
PY - 1999/1/1
Y1 - 1999/1/1
N2 - The test of an interaction potential for HF-argon recently determined from the spectroscopy of the Van der Waals complex requires accurate experimental widths and shifts cross sections. Since inconsistencies existed between previous measurements, collisional lineshapes were studied at T = 296 K by high-resolution Fourier transform spectroscopy for the 0-0, 0-1, and 0-2 bands. The accurate close-coupling molecular scattering calculations of Green and Hutson (1994. J. Chem. Phys. 100, 891) were extended to a complementary set of kinetic energies in order to check the thermal averaging procedure. Agreement between measured and computed room temperature cross sections is excellent for the three vibrational bands. This confirms the accuracy of the HF-argon surface and particularly its dependence on the HF vibrational level, which is sensitively probed both by the widths and by the shifts cross sections at high ji values.
AB - The test of an interaction potential for HF-argon recently determined from the spectroscopy of the Van der Waals complex requires accurate experimental widths and shifts cross sections. Since inconsistencies existed between previous measurements, collisional lineshapes were studied at T = 296 K by high-resolution Fourier transform spectroscopy for the 0-0, 0-1, and 0-2 bands. The accurate close-coupling molecular scattering calculations of Green and Hutson (1994. J. Chem. Phys. 100, 891) were extended to a complementary set of kinetic energies in order to check the thermal averaging procedure. Agreement between measured and computed room temperature cross sections is excellent for the three vibrational bands. This confirms the accuracy of the HF-argon surface and particularly its dependence on the HF vibrational level, which is sensitively probed both by the widths and by the shifts cross sections at high ji values.
KW - Fourier transform spectroscopy
KW - HF in a bath of argon
KW - Widths and shifts
UR - http://www.scopus.com/inward/record.url?scp=0001202865&partnerID=8YFLogxK
U2 - 10.1006/jmsp.1999.7903
DO - 10.1006/jmsp.1999.7903
M3 - Article
AN - SCOPUS:0001202865
VL - 198
SP - 249
EP - 256
JO - Journal of Molecular Spectroscopy
JF - Journal of Molecular Spectroscopy
SN - 0022-2852
IS - 2
ER -
ID: 28687786