DOI

  • I. M. Grigoriev
  • R. Le Doucen
  • J. Boissoles
  • B. Calil
  • C. Boulet
  • J. M. Hartmann
  • X. Bruet
  • M. L. Dubernet

The test of an interaction potential for HF-argon recently determined from the spectroscopy of the Van der Waals complex requires accurate experimental widths and shifts cross sections. Since inconsistencies existed between previous measurements, collisional lineshapes were studied at T = 296 K by high-resolution Fourier transform spectroscopy for the 0-0, 0-1, and 0-2 bands. The accurate close-coupling molecular scattering calculations of Green and Hutson (1994. J. Chem. Phys. 100, 891) were extended to a complementary set of kinetic energies in order to check the thermal averaging procedure. Agreement between measured and computed room temperature cross sections is excellent for the three vibrational bands. This confirms the accuracy of the HF-argon surface and particularly its dependence on the HF vibrational level, which is sensitively probed both by the widths and by the shifts cross sections at high ji values.

Язык оригиналаанглийский
Страницы (с-по)249-256
Число страниц8
ЖурналJournal of Molecular Spectroscopy
Том198
Номер выпуска2
DOI
СостояниеОпубликовано - 1 янв 1999

    Предметные области Scopus

  • Атомная и молекулярная физика и оптика
  • Спектроскопия
  • Физическая и теоретическая химия

ID: 28687786