Reverse Arene Sandwich Structures Based upon π-Hole⋅⋅⋅[M II ] (d 8 M=Pt, Pd) Interactions, where Positively Charged Metal Centers Play the Role of a Nucleophile

Anton V. Rozhkov, Mariya A. Krykova, Daniil M. Ivanov, Alexander S. Novikov, Anna A. Sinelshchikova, Marina V. Volostnykh, Mikhail A. Konovalov, Mikhail S. Grigoriev, Yulia G. Gorbunova, Vadim Yu Kukushkin

Результат исследований: Научные публикации в периодических изданияхстатьярецензирование

17 Цитирования (Scopus)
51 Загрузки (Pure)

Аннотация

The complexes [Pt(tpp)] (H 2 tpp=tetraphenylporphyrin), [M(acac) 2 ] (M=Pd, Pt, Hacac=acetylacetone), and [Pd(ba) 2 ] (Hba=benzoylacetone) were co-crystallized with highly electron-deficient arene systems to form reverse arene sandwich structures built by π-hole⋅⋅⋅[M II ] (d 8 M=Pt, Pd) interactions. The adduct [Pt(tpp)]⋅2 C 6 F 6 is monomeric, whereas the diketonate 1:1 adducts form columnar infinity 1D-stack assembled by simultaneous action of both π-hole⋅⋅⋅[M II ] and C⋅⋅⋅F interactions. The reverse sandwiches are based on noncovalent interactions and calculated ESP distributions indicate that in π-hole⋅⋅⋅[M II ] contacts, [M II ] plays the role of a nucleophile.

Язык оригиналаанглийский
Страницы (с-по)4164-4168
Число страниц5
ЖурналAngewandte Chemie - International Edition
Том58
Номер выпуска13
DOI
СостояниеОпубликовано - 22 мар 2019

Предметные области Scopus

  • Химия (все)
  • Катализ

Fingerprint Подробные сведения о темах исследования «Reverse Arene Sandwich Structures Based upon π-Hole⋅⋅⋅[M <sup>II</sup> ] (d <sup>8</sup> M=Pt, Pd) Interactions, where Positively Charged Metal Centers Play the Role of a Nucleophile». Вместе они формируют уникальный семантический отпечаток (fingerprint).

Цитировать