Reactivity of acyclic diaminocarbene ligands

Mikhail A. Kinzhalov, Konstantin V. Luzyanin

Результат исследований: Научные публикации в периодических изданияхОбзорная статья

Выдержка

Acyclic diaminocarbenes (ADCs) are powerful ligands with a broad application scope in organometallic chemistry, catalysis, photophysics and crystal engineering. Although the preparation and application of metal-ADC species are discussed in many reports, the reactivity of ADC ligands is much less scrutinised. However, studies emerged indicate that ADC ligands, in particular, those prepared via the metal-mediated nucleophilic addition to isocyanides, can be further converted into various post-functionalised derivatives. In this review, we attempt for the first time to rationalise the most important reactivity modes of metal-ADC species reported up to date.

Язык оригиналаанглийский
Номер статьи213014
ЖурналCoordination Chemistry Reviews
Том399
Ранняя дата в режиме онлайн3 сен 2019
DOI
СостояниеОпубликовано - 3 дек 2019

Отпечаток

reactivity
Metals
Ligands
ligands
Crystal engineering
metals
Cyanides
Organometallics
Catalysis
catalysis
engineering
chemistry
Derivatives
preparation
crystals

Предметные области Scopus

  • Химия (все)
  • Физическая и теоретическая химия
  • Неорганическая химия
  • Химия материалов

Цитировать

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Reactivity of acyclic diaminocarbene ligands. / Kinzhalov, Mikhail A.; Luzyanin, Konstantin V.

В: Coordination Chemistry Reviews, Том 399, 213014, 03.12.2019.

Результат исследований: Научные публикации в периодических изданияхОбзорная статья

TY - JOUR

T1 - Reactivity of acyclic diaminocarbene ligands

AU - Kinzhalov, Mikhail A.

AU - Luzyanin, Konstantin V.

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N2 - Acyclic diaminocarbenes (ADCs) are powerful ligands with a broad application scope in organometallic chemistry, catalysis, photophysics and crystal engineering. Although the preparation and application of metal-ADC species are discussed in many reports, the reactivity of ADC ligands is much less scrutinised. However, studies emerged indicate that ADC ligands, in particular, those prepared via the metal-mediated nucleophilic addition to isocyanides, can be further converted into various post-functionalised derivatives. In this review, we attempt for the first time to rationalise the most important reactivity modes of metal-ADC species reported up to date.

AB - Acyclic diaminocarbenes (ADCs) are powerful ligands with a broad application scope in organometallic chemistry, catalysis, photophysics and crystal engineering. Although the preparation and application of metal-ADC species are discussed in many reports, the reactivity of ADC ligands is much less scrutinised. However, studies emerged indicate that ADC ligands, in particular, those prepared via the metal-mediated nucleophilic addition to isocyanides, can be further converted into various post-functionalised derivatives. In this review, we attempt for the first time to rationalise the most important reactivity modes of metal-ADC species reported up to date.

KW - Acyclic diaminocarbene

KW - Carbene ligands

KW - Deprotonation

KW - Metal complexes

KW - Reactivity modes

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