Polar BaCl(ClO4)·H2O layered chloride perchlorate

D. O. Charkin, E. V. Nazarchuk, S. Yu Stefanovich, E. B. Djangurazov, A. I. Zadoya, O. I. Siidra

Результат исследований: Научные публикации в периодических изданияхстатья

1 цитирование (Scopus)

Выдержка

Synthesis and crystal structure of a polar layered chloride perchlorate, BaCl(ClO4)·H2O (1) where the chlorine atoms play two crystallographically different roles with ClVII centering the anionic [ClO4] tetrahedra, and Cl I centering the edge-sharing [ClBa4]7 + anion-centered tetrahedra is reported. SHG measurements confirm SHG activity of 1 as 5–6 SiO2 units. The polarity in the structure of 1 is resulted from the orientation of the perchlorate anions.

Язык оригиналаанглийский
Страницы (с-по)174-177
Число страниц4
ЖурналInorganic Chemistry Communications
Том84
DOI
СостояниеОпубликовано - 1 окт 2017

Отпечаток

perchlorates
tetrahedrons
Chlorides
Negative ions
chlorides
anions
Chlorine
Anions
chlorine
polarity
Crystal structure
Atoms
crystal structure
synthesis
atoms
perchlorate

Предметные области Scopus

  • Физическая и теоретическая химия
  • Неорганическая химия
  • Химия материалов

Цитировать

Charkin, D. O. ; Nazarchuk, E. V. ; Stefanovich, S. Yu ; Djangurazov, E. B. ; Zadoya, A. I. ; Siidra, O. I. / Polar BaCl(ClO4)·H2O layered chloride perchlorate. В: Inorganic Chemistry Communications. 2017 ; Том 84. стр. 174-177.
@article{37439b09af87400796d85c243da9008a,
title = "Polar BaCl(ClO4)·H2O layered chloride perchlorate",
abstract = "Synthesis and crystal structure of a polar layered chloride perchlorate, BaCl(ClO4)·H2O (1) where the chlorine atoms play two crystallographically different roles with ClVII centering the anionic [ClO4]− tetrahedra, and Cl− I centering the edge-sharing [ClBa4]7 + anion-centered tetrahedra is reported. SHG measurements confirm SHG activity of 1 as 5–6 SiO2 units. The polarity in the structure of 1 is resulted from the orientation of the perchlorate anions.",
keywords = "Anion-centered tetrahedra, Chloride, Perchlorate, Polar compounds, Single crystal X-ray diffraction",
author = "Charkin, {D. O.} and Nazarchuk, {E. V.} and Stefanovich, {S. Yu} and Djangurazov, {E. B.} and Zadoya, {A. I.} and Siidra, {O. I.}",
year = "2017",
month = "10",
day = "1",
doi = "10.1016/j.inoche.2017.08.022",
language = "English",
volume = "84",
pages = "174--177",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",

}

Polar BaCl(ClO4)·H2O layered chloride perchlorate. / Charkin, D. O.; Nazarchuk, E. V.; Stefanovich, S. Yu; Djangurazov, E. B.; Zadoya, A. I.; Siidra, O. I.

В: Inorganic Chemistry Communications, Том 84, 01.10.2017, стр. 174-177.

Результат исследований: Научные публикации в периодических изданияхстатья

TY - JOUR

T1 - Polar BaCl(ClO4)·H2O layered chloride perchlorate

AU - Charkin, D. O.

AU - Nazarchuk, E. V.

AU - Stefanovich, S. Yu

AU - Djangurazov, E. B.

AU - Zadoya, A. I.

AU - Siidra, O. I.

PY - 2017/10/1

Y1 - 2017/10/1

N2 - Synthesis and crystal structure of a polar layered chloride perchlorate, BaCl(ClO4)·H2O (1) where the chlorine atoms play two crystallographically different roles with ClVII centering the anionic [ClO4]− tetrahedra, and Cl− I centering the edge-sharing [ClBa4]7 + anion-centered tetrahedra is reported. SHG measurements confirm SHG activity of 1 as 5–6 SiO2 units. The polarity in the structure of 1 is resulted from the orientation of the perchlorate anions.

AB - Synthesis and crystal structure of a polar layered chloride perchlorate, BaCl(ClO4)·H2O (1) where the chlorine atoms play two crystallographically different roles with ClVII centering the anionic [ClO4]− tetrahedra, and Cl− I centering the edge-sharing [ClBa4]7 + anion-centered tetrahedra is reported. SHG measurements confirm SHG activity of 1 as 5–6 SiO2 units. The polarity in the structure of 1 is resulted from the orientation of the perchlorate anions.

KW - Anion-centered tetrahedra

KW - Chloride

KW - Perchlorate

KW - Polar compounds

KW - Single crystal X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=85028395661&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2017.08.022

DO - 10.1016/j.inoche.2017.08.022

M3 - Article

AN - SCOPUS:85028395661

VL - 84

SP - 174

EP - 177

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

ER -