Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Photoinduced chesorluminescence from radical processes on ZrO2 surfaces. / Andreev, N. S.; Emeline, A. V.; Khudnev, V. A.; Polikhova, S. A.; Ryabchuk, V. K.; Serpone, N.
в: Chemical Physics Letters, Том 325, № 1-3, 21.07.2000, стр. 288-292.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Photoinduced chesorluminescence from radical processes on ZrO2 surfaces
AU - Andreev, N. S.
AU - Emeline, A. V.
AU - Khudnev, V. A.
AU - Polikhova, S. A.
AU - Ryabchuk, V. K.
AU - Serpone, N.
PY - 2000/7/21
Y1 - 2000/7/21
N2 - Photoexcitation of ZrO2 particles causes luminescence (τ~15.0 s) which, after its termination, on addition of H2 causes emission of a light pulse that displays biphasic decay kinetics (τ1~0.9 s and τ2~15.5 s). The latter emission is referred to as a photoinduced chesorluminescence (PhICL). At 77 K, the longer-lived emission is thermally quenched. The shorter-lived emission is caused by electron trapping by the Va (anion vacancies) low energy traps; the longer-lived emission involves electron trapping by shallow traps, followed by detrapping and subsequent retrapping by the Va traps. Formation of highly energetic radical species is a necessary condition to observe PhICL emission.
AB - Photoexcitation of ZrO2 particles causes luminescence (τ~15.0 s) which, after its termination, on addition of H2 causes emission of a light pulse that displays biphasic decay kinetics (τ1~0.9 s and τ2~15.5 s). The latter emission is referred to as a photoinduced chesorluminescence (PhICL). At 77 K, the longer-lived emission is thermally quenched. The shorter-lived emission is caused by electron trapping by the Va (anion vacancies) low energy traps; the longer-lived emission involves electron trapping by shallow traps, followed by detrapping and subsequent retrapping by the Va traps. Formation of highly energetic radical species is a necessary condition to observe PhICL emission.
UR - http://www.scopus.com/inward/record.url?scp=0000726018&partnerID=8YFLogxK
U2 - 10.1016/S0009-2614(00)00648-5
DO - 10.1016/S0009-2614(00)00648-5
M3 - Article
AN - SCOPUS:0000726018
VL - 325
SP - 288
EP - 292
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 1-3
ER -
ID: 35144037