Organofluorine chemistry: Promising growth areas and challenges

Larisa V. Politanskaya, Galina A. Selivanova, Elena V. Panteleeva, Evgeny V. Tretyakov, Vyacheslav E. Platonov, Pavel V. Nikul'Shin, Andrey S. Vinogradov, Yaroslav V. Zonov, Victor M. Karpov, Tatyana V. Mezhenkova, Aleksander V. Vasilyev, Andrei B. Koldobskii, Olga S. Shilova, Sofia M. Morozova, Yanina V. Burgart, Evgeny V. Shchegolkov, Victor I. Saloutin, Vladimir B. Sokolov, Aleksey Yu Aksinenko, Valentine G. NenajdenkoMikhail Yu Moskalik, Vera V. Astakhova, Bagrat A. Shainyan, Andrey A. Tabolin, Sema L. Ioffe, Vasiliy M. Muzalevskiy, Elizaveta S. Balenkova, Alexey V. Shastin, Andrey A. Tyutyunov, Vladimir E. Boiko, Sergei M. Igumnov, Alexander D. Dilman, Nicolay Yu Adonin, Vadim V. Bardin, Salekh M. Masoud, Daria V. Vorobyeva, Sergey N. Osipov, Emiliya V. Nosova, Galina N. Lipunova, Valery N. Charushin, Darya O. Prima, Arkady G. Makarov, Andrey V. Zibarev, Boris A. Trofimov, Lyubov N. Sobenina, Kseniya V. Belyaeva, Vyacheslav Ya Sosnovskikh, Dmitrii L. Obydennov, Sergey A. Usachev

Результат исследований: Научные публикации в периодических изданияхОбзорная статья

9 Цитирования (Scopus)

Выдержка

Currently, the chemistry of organofluorine compounds is a leading and rapidly developing area of organic chemistry. Fluorine present in a molecule largely determines its specific chemical and biological properties. This thematic issue covers the trends of organofluorine chemistry that have been actively developed in Russia the last 15 ± 20 years. The review describes nucleophilic substitution and heterocyclization reactions involving fluorinated arenes and quinones and skeletal cationoid rearrangements in the polyfluoroarene series. The transformations involving CF3-substituted carbocations and radical cations are considered. Heterocyclization and oxidative addition reactions of trifluoroacetamide derivatives and trans- formations of the organic moiety in polyfluorinated organoboranes and borates with retention of the carbon - boron bond are discussed. Particular attention is devoted to catalytic olefination using freons as an efficient synthetic route to fluorinated compounds. The application of unsymmetrical fluorine-containing N-heterocyclic carbene ligands as catalysts for olefin metathesis is demonstrated. A variety of classes of organofluorine compounds are considered, in particular, polyfluorinated arenes and 1,2-diaminobenzenes, 1-halo-2-trifluoroacetylacetylenes, α-fluoronitro compounds, fluorinated heterocycles, 2-hydrazinylidene-1,3-dicarbonyl derivatives, imines and silanes. The potential practical applications of organofluorine compounds in fundamental organic chemistry, materials science and biomedicine are outlined.

Язык оригиналаанглийский
Страницы (с-по)425-569
Число страниц145
ЖурналRussian Chemical Reviews
Том88
Номер выпуска5
DOI
СостояниеОпубликовано - 1 янв 2019

Отпечаток

Fluorine
Chlorofluorocarbons
Derivatives
Silanes
Quinones
Borates
Addition reactions
Boron
Imines
Alkenes
Materials science
Cations
Substitution reactions
Carbon
Ligands
Catalysts
Molecules
Organic Chemistry
trifluoroacetamide
carbene

Предметные области Scopus

  • Химия (все)

Цитировать

Politanskaya, L. V., Selivanova, G. A., Panteleeva, E. V., Tretyakov, E. V., Platonov, V. E., Nikul'Shin, P. V., ... Usachev, S. A. (2019). Organofluorine chemistry: Promising growth areas and challenges. Russian Chemical Reviews, 88(5), 425-569. https://doi.org/10.1070/RCR4871
Politanskaya, Larisa V. ; Selivanova, Galina A. ; Panteleeva, Elena V. ; Tretyakov, Evgeny V. ; Platonov, Vyacheslav E. ; Nikul'Shin, Pavel V. ; Vinogradov, Andrey S. ; Zonov, Yaroslav V. ; Karpov, Victor M. ; Mezhenkova, Tatyana V. ; Vasilyev, Aleksander V. ; Koldobskii, Andrei B. ; Shilova, Olga S. ; Morozova, Sofia M. ; Burgart, Yanina V. ; Shchegolkov, Evgeny V. ; Saloutin, Victor I. ; Sokolov, Vladimir B. ; Aksinenko, Aleksey Yu ; Nenajdenko, Valentine G. ; Moskalik, Mikhail Yu ; Astakhova, Vera V. ; Shainyan, Bagrat A. ; Tabolin, Andrey A. ; Ioffe, Sema L. ; Muzalevskiy, Vasiliy M. ; Balenkova, Elizaveta S. ; Shastin, Alexey V. ; Tyutyunov, Andrey A. ; Boiko, Vladimir E. ; Igumnov, Sergei M. ; Dilman, Alexander D. ; Adonin, Nicolay Yu ; Bardin, Vadim V. ; Masoud, Salekh M. ; Vorobyeva, Daria V. ; Osipov, Sergey N. ; Nosova, Emiliya V. ; Lipunova, Galina N. ; Charushin, Valery N. ; Prima, Darya O. ; Makarov, Arkady G. ; Zibarev, Andrey V. ; Trofimov, Boris A. ; Sobenina, Lyubov N. ; Belyaeva, Kseniya V. ; Sosnovskikh, Vyacheslav Ya ; Obydennov, Dmitrii L. ; Usachev, Sergey A. / Organofluorine chemistry : Promising growth areas and challenges. В: Russian Chemical Reviews. 2019 ; Том 88, № 5. стр. 425-569.
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Politanskaya, LV, Selivanova, GA, Panteleeva, EV, Tretyakov, EV, Platonov, VE, Nikul'Shin, PV, Vinogradov, AS, Zonov, YV, Karpov, VM, Mezhenkova, TV, Vasilyev, AV, Koldobskii, AB, Shilova, OS, Morozova, SM, Burgart, YV, Shchegolkov, EV, Saloutin, VI, Sokolov, VB, Aksinenko, AY, Nenajdenko, VG, Moskalik, MY, Astakhova, VV, Shainyan, BA, Tabolin, AA, Ioffe, SL, Muzalevskiy, VM, Balenkova, ES, Shastin, AV, Tyutyunov, AA, Boiko, VE, Igumnov, SM, Dilman, AD, Adonin, NY, Bardin, VV, Masoud, SM, Vorobyeva, DV, Osipov, SN, Nosova, EV, Lipunova, GN, Charushin, VN, Prima, DO, Makarov, AG, Zibarev, AV, Trofimov, BA, Sobenina, LN, Belyaeva, KV, Sosnovskikh, VY, Obydennov, DL & Usachev, SA 2019, 'Organofluorine chemistry: Promising growth areas and challenges', Russian Chemical Reviews, том. 88, № 5, стр. 425-569. https://doi.org/10.1070/RCR4871

Organofluorine chemistry : Promising growth areas and challenges. / Politanskaya, Larisa V.; Selivanova, Galina A.; Panteleeva, Elena V.; Tretyakov, Evgeny V.; Platonov, Vyacheslav E.; Nikul'Shin, Pavel V.; Vinogradov, Andrey S.; Zonov, Yaroslav V.; Karpov, Victor M.; Mezhenkova, Tatyana V.; Vasilyev, Aleksander V.; Koldobskii, Andrei B.; Shilova, Olga S.; Morozova, Sofia M.; Burgart, Yanina V.; Shchegolkov, Evgeny V.; Saloutin, Victor I.; Sokolov, Vladimir B.; Aksinenko, Aleksey Yu; Nenajdenko, Valentine G.; Moskalik, Mikhail Yu; Astakhova, Vera V.; Shainyan, Bagrat A.; Tabolin, Andrey A.; Ioffe, Sema L.; Muzalevskiy, Vasiliy M.; Balenkova, Elizaveta S.; Shastin, Alexey V.; Tyutyunov, Andrey A.; Boiko, Vladimir E.; Igumnov, Sergei M.; Dilman, Alexander D.; Adonin, Nicolay Yu; Bardin, Vadim V.; Masoud, Salekh M.; Vorobyeva, Daria V.; Osipov, Sergey N.; Nosova, Emiliya V.; Lipunova, Galina N.; Charushin, Valery N.; Prima, Darya O.; Makarov, Arkady G.; Zibarev, Andrey V.; Trofimov, Boris A.; Sobenina, Lyubov N.; Belyaeva, Kseniya V.; Sosnovskikh, Vyacheslav Ya; Obydennov, Dmitrii L.; Usachev, Sergey A.

В: Russian Chemical Reviews, Том 88, № 5, 01.01.2019, стр. 425-569.

Результат исследований: Научные публикации в периодических изданияхОбзорная статья

TY - JOUR

T1 - Organofluorine chemistry

T2 - Promising growth areas and challenges

AU - Politanskaya, Larisa V.

AU - Selivanova, Galina A.

AU - Panteleeva, Elena V.

AU - Tretyakov, Evgeny V.

AU - Platonov, Vyacheslav E.

AU - Nikul'Shin, Pavel V.

AU - Vinogradov, Andrey S.

AU - Zonov, Yaroslav V.

AU - Karpov, Victor M.

AU - Mezhenkova, Tatyana V.

AU - Vasilyev, Aleksander V.

AU - Koldobskii, Andrei B.

AU - Shilova, Olga S.

AU - Morozova, Sofia M.

AU - Burgart, Yanina V.

AU - Shchegolkov, Evgeny V.

AU - Saloutin, Victor I.

AU - Sokolov, Vladimir B.

AU - Aksinenko, Aleksey Yu

AU - Nenajdenko, Valentine G.

AU - Moskalik, Mikhail Yu

AU - Astakhova, Vera V.

AU - Shainyan, Bagrat A.

AU - Tabolin, Andrey A.

AU - Ioffe, Sema L.

AU - Muzalevskiy, Vasiliy M.

AU - Balenkova, Elizaveta S.

AU - Shastin, Alexey V.

AU - Tyutyunov, Andrey A.

AU - Boiko, Vladimir E.

AU - Igumnov, Sergei M.

AU - Dilman, Alexander D.

AU - Adonin, Nicolay Yu

AU - Bardin, Vadim V.

AU - Masoud, Salekh M.

AU - Vorobyeva, Daria V.

AU - Osipov, Sergey N.

AU - Nosova, Emiliya V.

AU - Lipunova, Galina N.

AU - Charushin, Valery N.

AU - Prima, Darya O.

AU - Makarov, Arkady G.

AU - Zibarev, Andrey V.

AU - Trofimov, Boris A.

AU - Sobenina, Lyubov N.

AU - Belyaeva, Kseniya V.

AU - Sosnovskikh, Vyacheslav Ya

AU - Obydennov, Dmitrii L.

AU - Usachev, Sergey A.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - Currently, the chemistry of organofluorine compounds is a leading and rapidly developing area of organic chemistry. Fluorine present in a molecule largely determines its specific chemical and biological properties. This thematic issue covers the trends of organofluorine chemistry that have been actively developed in Russia the last 15 ± 20 years. The review describes nucleophilic substitution and heterocyclization reactions involving fluorinated arenes and quinones and skeletal cationoid rearrangements in the polyfluoroarene series. The transformations involving CF3-substituted carbocations and radical cations are considered. Heterocyclization and oxidative addition reactions of trifluoroacetamide derivatives and trans- formations of the organic moiety in polyfluorinated organoboranes and borates with retention of the carbon - boron bond are discussed. Particular attention is devoted to catalytic olefination using freons as an efficient synthetic route to fluorinated compounds. The application of unsymmetrical fluorine-containing N-heterocyclic carbene ligands as catalysts for olefin metathesis is demonstrated. A variety of classes of organofluorine compounds are considered, in particular, polyfluorinated arenes and 1,2-diaminobenzenes, 1-halo-2-trifluoroacetylacetylenes, α-fluoronitro compounds, fluorinated heterocycles, 2-hydrazinylidene-1,3-dicarbonyl derivatives, imines and silanes. The potential practical applications of organofluorine compounds in fundamental organic chemistry, materials science and biomedicine are outlined.

AB - Currently, the chemistry of organofluorine compounds is a leading and rapidly developing area of organic chemistry. Fluorine present in a molecule largely determines its specific chemical and biological properties. This thematic issue covers the trends of organofluorine chemistry that have been actively developed in Russia the last 15 ± 20 years. The review describes nucleophilic substitution and heterocyclization reactions involving fluorinated arenes and quinones and skeletal cationoid rearrangements in the polyfluoroarene series. The transformations involving CF3-substituted carbocations and radical cations are considered. Heterocyclization and oxidative addition reactions of trifluoroacetamide derivatives and trans- formations of the organic moiety in polyfluorinated organoboranes and borates with retention of the carbon - boron bond are discussed. Particular attention is devoted to catalytic olefination using freons as an efficient synthetic route to fluorinated compounds. The application of unsymmetrical fluorine-containing N-heterocyclic carbene ligands as catalysts for olefin metathesis is demonstrated. A variety of classes of organofluorine compounds are considered, in particular, polyfluorinated arenes and 1,2-diaminobenzenes, 1-halo-2-trifluoroacetylacetylenes, α-fluoronitro compounds, fluorinated heterocycles, 2-hydrazinylidene-1,3-dicarbonyl derivatives, imines and silanes. The potential practical applications of organofluorine compounds in fundamental organic chemistry, materials science and biomedicine are outlined.

UR - http://www.scopus.com/inward/record.url?scp=85066251313&partnerID=8YFLogxK

U2 - 10.1070/RCR4871

DO - 10.1070/RCR4871

M3 - Review article

AN - SCOPUS:85066251313

VL - 88

SP - 425

EP - 569

JO - Russian Chemical Reviews

JF - Russian Chemical Reviews

SN - 0036-021X

IS - 5

ER -

Politanskaya LV, Selivanova GA, Panteleeva EV, Tretyakov EV, Platonov VE, Nikul'Shin PV и соавт. Organofluorine chemistry: Promising growth areas and challenges. Russian Chemical Reviews. 2019 Янв. 1;88(5):425-569. https://doi.org/10.1070/RCR4871