Observation of perturbations in the rovibronic transition probabilities for the (4d)r3Πg- , (4d) s3 Δg- → (2p) c3Π u ± band systems of the H2 molecule

S. A. Astashkevich, B. P. Lavrov, A. V. Modin, I. S. Umrikhin

Результат исследований: Научные публикации в периодических изданияхстатьярецензирование

2 Цитирования (Scopus)

Аннотация

The ratios of the radiative transition probabilities for the lines of the P, Q, and R branches of the (4d)r 3Π g - , (4d)s 3Δ g - → (2p) c 3Π u ± band systems of the H 2 molecule have been measured for the first time. Significant (to two orders of magnitudes) differences are found between the experimental values and the adiabatic theory predictions. It is established that the results of the nonadiabatic calculation performed by us in the pure-precession approximation taking into account the electronic-rotational interaction of the 4d 3Πg and 4d 3Δg states are in agreement with the experimental data. The optimal energies of rovibronic levels of the r 3Π g - , s 3Δ g - , c 3Π u - , and c 3Π u + states have been found and reidentification of 11 from 54 spectral lines, assigned previously to the (0-0) and (1-1) bands, was performed.

Язык оригиналаанглийский
Страницы (с-по)363-366
Число страниц4
ЖурналOptics and Spectroscopy (English translation of Optika i Spektroskopiya)
Том102
Номер выпуска3
DOI
СостояниеОпубликовано - 1 мар 2007

Предметные области Scopus

  • Электроника, оптика и магнитные материалы
  • Атомная и молекулярная физика и оптика

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Подробные сведения о темах исследования «Observation of perturbations in the rovibronic transition probabilities for the (4d)r<sup>3</sup>Π<sub>g</sub><sup>-</sup> , (4d) s<sup>3</sup> Δ<sub>g</sub><sup>-</sup> → (2p) c<sup>3</sup>Π <sub>u</sub> <sup>±</sup> band systems of the H<sub>2</sub> molecule». Вместе они формируют уникальный семантический отпечаток (fingerprint).

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