New Nickel(II) Complexes with Tetradentate Schiff Bases Containing Electron-Acceptor Substituents

Dmitry Kurchavov, Михаил Павлович Карушев, A.M. Timonov

Результат исследований: Научные публикации в периодических изданияхписьмо/краткое сообщениенаучнаярецензирование

Выдержка

Complexes [Ni(3-NO2SalEn)] and [Ni(3-NO2SaltmEn)] were synthesized and identified, and polymers based on them were obtained. It was found with the help of voltammetry that the introduction of nitro groups in the complexes shifts their redox activity in the direction of positive potentials; it was shown by in situ quartz microgravimetry and in situ absorption spectroscopy methods that fragments of the polymer complexes under study can undergo reversible two-electron oxidation at the expense of formation of polarons and bipolarons in the ligand surrounding.
Язык оригиналаанглийский
Страницы (с-по)1553
Число страниц3
ЖурналRussian Journal of General Chemistry
Том88
Номер выпуска7
DOI
СостояниеОпубликовано - 4 сен 2018

Цитировать

Kurchavov, Dmitry ; Карушев, Михаил Павлович ; Timonov, A.M. / New Nickel(II) Complexes with Tetradentate Schiff Bases Containing Electron-Acceptor Substituents. В: Russian Journal of General Chemistry. 2018 ; Том 88, № 7. стр. 1553.
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abstract = "Complexes [Ni(3-NO2SalEn)] and [Ni(3-NO2SaltmEn)] were synthesized and identified, and polymers based on them were obtained. It was found with the help of voltammetry that the introduction of nitro groups in the complexes shifts their redox activity in the direction of positive potentials; it was shown by in situ quartz microgravimetry and in situ absorption spectroscopy methods that fragments of the polymer complexes under study can undergo reversible two-electron oxidation at the expense of formation of polarons and bipolarons in the ligand surrounding.",
author = "Dmitry Kurchavov and Карушев, {Михаил Павлович} and A.M. Timonov",
year = "2018",
month = "9",
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doi = "10.1134/S1070363218070332",
language = "English",
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New Nickel(II) Complexes with Tetradentate Schiff Bases Containing Electron-Acceptor Substituents. / Kurchavov, Dmitry; Карушев, Михаил Павлович; Timonov, A.M.

В: Russian Journal of General Chemistry, Том 88, № 7, 04.09.2018, стр. 1553.

Результат исследований: Научные публикации в периодических изданияхписьмо/краткое сообщениенаучнаярецензирование

TY - JOUR

T1 - New Nickel(II) Complexes with Tetradentate Schiff Bases Containing Electron-Acceptor Substituents

AU - Kurchavov, Dmitry

AU - Карушев, Михаил Павлович

AU - Timonov, A.M.

PY - 2018/9/4

Y1 - 2018/9/4

N2 - Complexes [Ni(3-NO2SalEn)] and [Ni(3-NO2SaltmEn)] were synthesized and identified, and polymers based on them were obtained. It was found with the help of voltammetry that the introduction of nitro groups in the complexes shifts their redox activity in the direction of positive potentials; it was shown by in situ quartz microgravimetry and in situ absorption spectroscopy methods that fragments of the polymer complexes under study can undergo reversible two-electron oxidation at the expense of formation of polarons and bipolarons in the ligand surrounding.

AB - Complexes [Ni(3-NO2SalEn)] and [Ni(3-NO2SaltmEn)] were synthesized and identified, and polymers based on them were obtained. It was found with the help of voltammetry that the introduction of nitro groups in the complexes shifts their redox activity in the direction of positive potentials; it was shown by in situ quartz microgravimetry and in situ absorption spectroscopy methods that fragments of the polymer complexes under study can undergo reversible two-electron oxidation at the expense of formation of polarons and bipolarons in the ligand surrounding.

U2 - 10.1134/S1070363218070332

DO - 10.1134/S1070363218070332

M3 - Letter

VL - 88

SP - 1553

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 7

ER -