Standard

New calcium perrhenates: synthesis and crystal structures of Ca(ReO4)2 and K2Ca3(ReO4)8·4H2O. / Чаркин, Дмитрий Олегович; Сийдра, Олег Иоханнесович; Назарчук, Евгений Васильевич; Борисов, Артем Сергеевич; Байкина, Анна Сергеевна.

в: Zeitschrift fur Kristallographie - Crystalline Materials, Том 240, № 5-6, 08.2025, стр. 191-196.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

APA

Vancouver

Author

BibTeX

@article{9eb1138153864d3ea0458439d8b5313f,
title = "New calcium perrhenates: synthesis and crystal structures of Ca(ReO4)2 and K2Ca3(ReO4)8·4H2O",
abstract = "Single crystals of two new calcium perrhenates, anhydrous Ca(ReO4)2 (1) and K2Ca3(ReO4)8·4H2O (2), were prepared during solid-state and solution attempts to prepare the potassium analog of NaCa(ReO4)3. Both structures can be regarded as frameworks comprised of vertex-sharing CaO8 and ReO4 polyhedra. 1 is a complete structural analog of Sr(ReO4)2 while 2 corresponds to its own structure type. It is also the first hydrated binary perrhenate to date. We discuss the similarities and differences in the structures of alkaline earth perrhenates and pertechnetates; existence of more complex and elegant metal-perrhenate architectures is predicted.",
keywords = "calcium, crystal structure, perrhenates, solid-state synthesis",
author = "Чаркин, {Дмитрий Олегович} and Сийдра, {Олег Иоханнесович} and Назарчук, {Евгений Васильевич} and Борисов, {Артем Сергеевич} and Байкина, {Анна Сергеевна}",
year = "2025",
month = aug,
doi = "10.1515/zkri-2025-0008",
language = "English",
volume = "240",
pages = "191--196",
journal = "Zeitschrift fur Kristallographie - Crystalline Materials",
issn = "2194-4946",
publisher = "De Gruyter",
number = "5-6",

}

RIS

TY - JOUR

T1 - New calcium perrhenates: synthesis and crystal structures of Ca(ReO4)2 and K2Ca3(ReO4)8·4H2O

AU - Чаркин, Дмитрий Олегович

AU - Сийдра, Олег Иоханнесович

AU - Назарчук, Евгений Васильевич

AU - Борисов, Артем Сергеевич

AU - Байкина, Анна Сергеевна

PY - 2025/8

Y1 - 2025/8

N2 - Single crystals of two new calcium perrhenates, anhydrous Ca(ReO4)2 (1) and K2Ca3(ReO4)8·4H2O (2), were prepared during solid-state and solution attempts to prepare the potassium analog of NaCa(ReO4)3. Both structures can be regarded as frameworks comprised of vertex-sharing CaO8 and ReO4 polyhedra. 1 is a complete structural analog of Sr(ReO4)2 while 2 corresponds to its own structure type. It is also the first hydrated binary perrhenate to date. We discuss the similarities and differences in the structures of alkaline earth perrhenates and pertechnetates; existence of more complex and elegant metal-perrhenate architectures is predicted.

AB - Single crystals of two new calcium perrhenates, anhydrous Ca(ReO4)2 (1) and K2Ca3(ReO4)8·4H2O (2), were prepared during solid-state and solution attempts to prepare the potassium analog of NaCa(ReO4)3. Both structures can be regarded as frameworks comprised of vertex-sharing CaO8 and ReO4 polyhedra. 1 is a complete structural analog of Sr(ReO4)2 while 2 corresponds to its own structure type. It is also the first hydrated binary perrhenate to date. We discuss the similarities and differences in the structures of alkaline earth perrhenates and pertechnetates; existence of more complex and elegant metal-perrhenate architectures is predicted.

KW - calcium

KW - crystal structure

KW - perrhenates

KW - solid-state synthesis

UR - https://www.degruyterbrill.com/document/doi/10.1515/zkri-2025-0008/html

UR - https://www.mendeley.com/catalogue/9c27bce2-c63b-3da4-be80-5b2e4f750329/

U2 - 10.1515/zkri-2025-0008

DO - 10.1515/zkri-2025-0008

M3 - Article

VL - 240

SP - 191

EP - 196

JO - Zeitschrift fur Kristallographie - Crystalline Materials

JF - Zeitschrift fur Kristallographie - Crystalline Materials

SN - 2194-4946

IS - 5-6

ER -

ID: 135474485