Near infrared spectral studies of aqueous solutions of metal perchlorates in groups I A, II A, II B, III A and III B of the Periodic Table

A.G. Davidian, A.G. Kudrev, L.A. Myund, M.K. Khripun

Результат исследований: Научные публикации в периодических изданияхстатья

6 Цитирования (Scopus)

Выдержка

Chemometrics of NIR spectra of aqueous salt solutions M(ClO4)n, where Mn+: Li+, Na+, Mg2+, Ca2+, Sr2+, Ba2+, Zn2+, Cd2+, Al3+, Ga3+, In3+, Sc3+, Y3+, La3+ were used to establish the effect of the cation nature on the structure of aqueous electrolytes solutions. Principal component analysis showed that near infrared (NIR) spectra of the systems under study are grouped into clusters. It was found that the values of the eutectic concentrations of aqueous salt solutions and the polarising powers of cations correlate. The combined use of NIR spectroscopy, chemometrics of the spectral data and a generalised phenomenological model of the structure of aqueous electrolytes solutions is a new approach to studying of the structure of concentrated solutions. © IM Publications LLP 2014.
Язык оригиналаанглийский
Страницы (с-по)27-34
ЖурналJournal of Near Infrared Spectroscopy
Том22
Номер выпуска1
DOI
СостояниеОпубликовано - 2014

Отпечаток

Perchlorates
Metals
Infrared radiation
Electrolytes
Cations
Salts
Near infrared spectroscopy
Principal component analysis
Eutectics

Цитировать

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title = "Near infrared spectral studies of aqueous solutions of metal perchlorates in groups I A, II A, II B, III A and III B of the Periodic Table",
abstract = "Chemometrics of NIR spectra of aqueous salt solutions M(ClO4)n, where Mn+: Li+, Na+, Mg2+, Ca2+, Sr2+, Ba2+, Zn2+, Cd2+, Al3+, Ga3+, In3+, Sc3+, Y3+, La3+ were used to establish the effect of the cation nature on the structure of aqueous electrolytes solutions. Principal component analysis showed that near infrared (NIR) spectra of the systems under study are grouped into clusters. It was found that the values of the eutectic concentrations of aqueous salt solutions and the polarising powers of cations correlate. The combined use of NIR spectroscopy, chemometrics of the spectral data and a generalised phenomenological model of the structure of aqueous electrolytes solutions is a new approach to studying of the structure of concentrated solutions. {\circledC} IM Publications LLP 2014.",
author = "A.G. Davidian and A.G. Kudrev and L.A. Myund and M.K. Khripun",
year = "2014",
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Near infrared spectral studies of aqueous solutions of metal perchlorates in groups I A, II A, II B, III A and III B of the Periodic Table. / Davidian, A.G.; Kudrev, A.G.; Myund, L.A.; Khripun, M.K.

В: Journal of Near Infrared Spectroscopy, Том 22, № 1, 2014, стр. 27-34.

Результат исследований: Научные публикации в периодических изданияхстатья

TY - JOUR

T1 - Near infrared spectral studies of aqueous solutions of metal perchlorates in groups I A, II A, II B, III A and III B of the Periodic Table

AU - Davidian, A.G.

AU - Kudrev, A.G.

AU - Myund, L.A.

AU - Khripun, M.K.

PY - 2014

Y1 - 2014

N2 - Chemometrics of NIR spectra of aqueous salt solutions M(ClO4)n, where Mn+: Li+, Na+, Mg2+, Ca2+, Sr2+, Ba2+, Zn2+, Cd2+, Al3+, Ga3+, In3+, Sc3+, Y3+, La3+ were used to establish the effect of the cation nature on the structure of aqueous electrolytes solutions. Principal component analysis showed that near infrared (NIR) spectra of the systems under study are grouped into clusters. It was found that the values of the eutectic concentrations of aqueous salt solutions and the polarising powers of cations correlate. The combined use of NIR spectroscopy, chemometrics of the spectral data and a generalised phenomenological model of the structure of aqueous electrolytes solutions is a new approach to studying of the structure of concentrated solutions. © IM Publications LLP 2014.

AB - Chemometrics of NIR spectra of aqueous salt solutions M(ClO4)n, where Mn+: Li+, Na+, Mg2+, Ca2+, Sr2+, Ba2+, Zn2+, Cd2+, Al3+, Ga3+, In3+, Sc3+, Y3+, La3+ were used to establish the effect of the cation nature on the structure of aqueous electrolytes solutions. Principal component analysis showed that near infrared (NIR) spectra of the systems under study are grouped into clusters. It was found that the values of the eutectic concentrations of aqueous salt solutions and the polarising powers of cations correlate. The combined use of NIR spectroscopy, chemometrics of the spectral data and a generalised phenomenological model of the structure of aqueous electrolytes solutions is a new approach to studying of the structure of concentrated solutions. © IM Publications LLP 2014.

U2 - 10.1255/jnirs.1090

DO - 10.1255/jnirs.1090

M3 - Article

VL - 22

SP - 27

EP - 34

JO - Journal of Near Infrared Spectroscopy

JF - Journal of Near Infrared Spectroscopy

SN - 0967-0335

IS - 1

ER -