Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Mixed Uranyl Sulfate-Selenates: Evolution of Structural Topology and Complexity vs Chemical Composition. / Gurzhiy, Vladislav V.; Tyumentseva, Olga S.; Krivovichev, Sergey V.; Krivovichev, Vladimir G.; Tananaev, Ivan G.
в: Crystal Growth and Design, Том 16, № 8, 23.06.2016, стр. 4482-4492.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Mixed Uranyl Sulfate-Selenates: Evolution of Structural Topology and Complexity vs Chemical Composition
AU - Gurzhiy, Vladislav V.
AU - Tyumentseva, Olga S.
AU - Krivovichev, Sergey V.
AU - Krivovichev, Vladimir G.
AU - Tananaev, Ivan G.
PY - 2016/6/23
Y1 - 2016/6/23
N2 - © 2016 American Chemical Society.Phase formation in the aqueous system of uranyl nitrate, potassium hydroxide, and variable amounts of sulfuric and selenic acids has been investigated. Four different types of crystalline phases with variable S and Se contents were isolated and characterized using single-crystal X-ray diffraction (XRD) and IR spectroscopy. Topological analysis and information-based complexity calculations demonstrated the following: (a) the absence of a continuous solid solution in the system, (b) the absence of isotypic sulfate and selenate phases, and (c) the discovery of two layered topologies unprecedented among inorganic oxysalts.
AB - © 2016 American Chemical Society.Phase formation in the aqueous system of uranyl nitrate, potassium hydroxide, and variable amounts of sulfuric and selenic acids has been investigated. Four different types of crystalline phases with variable S and Se contents were isolated and characterized using single-crystal X-ray diffraction (XRD) and IR spectroscopy. Topological analysis and information-based complexity calculations demonstrated the following: (a) the absence of a continuous solid solution in the system, (b) the absence of isotypic sulfate and selenate phases, and (c) the discovery of two layered topologies unprecedented among inorganic oxysalts.
U2 - 10.1021/acs.cgd.6b00611
DO - 10.1021/acs.cgd.6b00611
M3 - Article
VL - 16
SP - 4482
EP - 4492
JO - Crystal Growth and Design
JF - Crystal Growth and Design
SN - 1528-7483
IS - 8
ER -
ID: 7927939