Аннотация
Based on the line-space quantum formalism, the potential of Resonant Four-Wave Mixing spectroscopy
as a new tool to study rotational and translational anisotropy of photofragments produced by absorption
of plane-polarized photons is theoretically addressed. Synergy of the flexible polarization setup, fine
quantum state resolution and of the possibility to study translational recoil distributions, makes the tool
unsurpassed among the all-optical means to interrogate the photofragment states. It allows to directly
separate signals induced by the rotational anisotropy which remain silent in the most of laser-induced
fluorescence responses and thus opens new ways to study rotational helicity, a crucial signature of the
photolysis pathway.
Язык оригинала | английский |
---|---|
Страницы (с-по) | 103-107 |
Число страниц | 5 |
Журнал | Chemical Physics Letters |
Том | 673 |
DOI | |
Состояние | Опубликовано - 2017 |
Предметные области Scopus
- Химия (все)