Isocyanide metal complexes in catalysis

Kamran T. Mahmudov, Vadim Yu Kukushkin, Atash V. Gurbanov, Mikhail A. Kinzhalov, Vadim P. Boyarskiy, M. Fátima C.Guedes da Silva, Armando J.L. Pombeiro

Результат исследований: Научные публикации в периодических изданияхОбзорная статья

3 Цитирования (Scopus)

Выдержка

The catalytic applications of isocyanide metal systems (from early to late transition metals) for organic transformations were systematically reviewed, and the studied transformations are also classified by type regardless of the metal center. A broad range of catalytic reactions of organic substrates has been developed including reactions of alkenes and alkynes, functionalization of E–H and E–E to multiple bonds, alkyl- and aryl-halides activation, nucleophilic addition, electron transfer catalysis, and photochemical reactions. This report gives a general overview of reaction routes, mechanisms, and driving forces and highlights the potential of isocyanide metal species, drawing attention to emerging putative targets.

Язык оригиналаанглийский
Страницы (с-по)65-89
Число страниц25
ЖурналCoordination Chemistry Reviews
Том384
DOI
СостояниеОпубликовано - 1 апр 2019

Отпечаток

Coordination Complexes
Cyanides
Metal complexes
Catalysis
catalysis
Metals
halides
metals
general overviews
Alkynes
Photochemical reactions
Alkenes
alkynes
photochemical reactions
alkenes
Olefins
Transition metals
emerging
electron transfer
Chemical activation

Предметные области Scopus

  • Химия материалов
  • Неорганическая химия
  • Физическая и теоретическая химия

Цитировать

Mahmudov, Kamran T. ; Kukushkin, Vadim Yu ; Gurbanov, Atash V. ; Kinzhalov, Mikhail A. ; Boyarskiy, Vadim P. ; da Silva, M. Fátima C.Guedes ; Pombeiro, Armando J.L. / Isocyanide metal complexes in catalysis. В: Coordination Chemistry Reviews. 2019 ; Том 384. стр. 65-89.
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abstract = "The catalytic applications of isocyanide metal systems (from early to late transition metals) for organic transformations were systematically reviewed, and the studied transformations are also classified by type regardless of the metal center. A broad range of catalytic reactions of organic substrates has been developed including reactions of alkenes and alkynes, functionalization of E–H and E–E to multiple bonds, alkyl- and aryl-halides activation, nucleophilic addition, electron transfer catalysis, and photochemical reactions. This report gives a general overview of reaction routes, mechanisms, and driving forces and highlights the potential of isocyanide metal species, drawing attention to emerging putative targets.",
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Isocyanide metal complexes in catalysis. / Mahmudov, Kamran T.; Kukushkin, Vadim Yu; Gurbanov, Atash V.; Kinzhalov, Mikhail A.; Boyarskiy, Vadim P.; da Silva, M. Fátima C.Guedes; Pombeiro, Armando J.L.

В: Coordination Chemistry Reviews, Том 384, 01.04.2019, стр. 65-89.

Результат исследований: Научные публикации в периодических изданияхОбзорная статья

TY - JOUR

T1 - Isocyanide metal complexes in catalysis

AU - Mahmudov, Kamran T.

AU - Kukushkin, Vadim Yu

AU - Gurbanov, Atash V.

AU - Kinzhalov, Mikhail A.

AU - Boyarskiy, Vadim P.

AU - da Silva, M. Fátima C.Guedes

AU - Pombeiro, Armando J.L.

PY - 2019/4/1

Y1 - 2019/4/1

N2 - The catalytic applications of isocyanide metal systems (from early to late transition metals) for organic transformations were systematically reviewed, and the studied transformations are also classified by type regardless of the metal center. A broad range of catalytic reactions of organic substrates has been developed including reactions of alkenes and alkynes, functionalization of E–H and E–E to multiple bonds, alkyl- and aryl-halides activation, nucleophilic addition, electron transfer catalysis, and photochemical reactions. This report gives a general overview of reaction routes, mechanisms, and driving forces and highlights the potential of isocyanide metal species, drawing attention to emerging putative targets.

AB - The catalytic applications of isocyanide metal systems (from early to late transition metals) for organic transformations were systematically reviewed, and the studied transformations are also classified by type regardless of the metal center. A broad range of catalytic reactions of organic substrates has been developed including reactions of alkenes and alkynes, functionalization of E–H and E–E to multiple bonds, alkyl- and aryl-halides activation, nucleophilic addition, electron transfer catalysis, and photochemical reactions. This report gives a general overview of reaction routes, mechanisms, and driving forces and highlights the potential of isocyanide metal species, drawing attention to emerging putative targets.

KW - Homogeneous and heterogeneous catalysis

KW - Isocyanide metal complexes

KW - Metal-catalyzed and metal-mediated reactions

KW - Organic transformations

KW - COORDINATION CHEMISTRY

KW - COPPER-ISONITRILE COMPLEX

KW - PALLADIUM COMPLEXES

KW - SYNTHETIC REACTIONS

KW - TRANSFER HYDROGENATION

KW - CYCLIC-COMPOUNDS

KW - RADICAL-ADDITION

KW - TERT-ALKYL ISOCYANIDE

KW - STEREOSELECTIVE-SYNTHESIS

KW - INTRAMOLECULAR BIS-SILYLATION

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U2 - 10.1016/j.ccr.2019.01.002

DO - 10.1016/j.ccr.2019.01.002

M3 - Review article

AN - SCOPUS:85060550008

VL - 384

SP - 65

EP - 89

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

SN - 0010-8545

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