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Isobaric heat capacity and standard thermodynamic properties of cation-ordered layered perovskite-like oxides NaLnTiO4 and A2Ln2Ti3O10 (A = H, Na, K; Ln = La, Nd, Gd). / Sankovich, Anna M.; Myshkovskaia, Tatiana D.; Markin, Alexey V.; Smirnova, Natalia N.; Zvereva, Irina A.
в: Thermochimica Acta, Том 686, 178533, 04.2020.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Isobaric heat capacity and standard thermodynamic properties of cation-ordered layered perovskite-like oxides NaLnTiO4 and A2Ln2Ti3O10 (A = H, Na, K; Ln = La, Nd, Gd)
AU - Sankovich, Anna M.
AU - Myshkovskaia, Tatiana D.
AU - Markin, Alexey V.
AU - Smirnova, Natalia N.
AU - Zvereva, Irina A.
N1 - Funding Information: This work was financially supported by Russian Foundation for Basic Research (N 18-03-00915) and Ministry of Science and Higher Education of the Russian Federation (Contract No. 4.8337.2017/BCh). Measurements of the heat capacity were performed in Lobachevsky State University of Nizhni Novgorod. TG-study was carried out in the Thermogravimetric and Calorimetric Research Centre, powder X-ray study and X-ray photoelectron investigation were carried out in the X-ray Diffraction Centre and Centre for Physical Methods of Surface Investigation of St. Petersburg State University. Publisher Copyright: © 2020 Elsevier B.V. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/4
Y1 - 2020/4
N2 - The heat capacities of protonated layered perovskite-like oxides H1.64K0.36Nd2Ti3O10·0.61 H2O and H1.89K0.11Nd2Ti3O10·0.60 H2O were measured by precision adiabatic vacuum calorimetry over the temperature range of (6–300) K. The standard thermodynamic functions: molar heat capacity, enthalpy, entropy, and the Gibbs energy of the compounds were evaluated from the experimental data of the heat capacities over the temperature range of T = (6–300) K. The deviation of experimental points from fitting curves obtained on the basis of Debye's theory. The overview on low-temperature heat capacity and standard thermodynamic properties of cation-ordered layered perovskite-like titanates NaLnTiO4 and A2Ln2Ti3O10 (A=H, Na, K; Ln=La, Nd, Gd) is present.
AB - The heat capacities of protonated layered perovskite-like oxides H1.64K0.36Nd2Ti3O10·0.61 H2O and H1.89K0.11Nd2Ti3O10·0.60 H2O were measured by precision adiabatic vacuum calorimetry over the temperature range of (6–300) K. The standard thermodynamic functions: molar heat capacity, enthalpy, entropy, and the Gibbs energy of the compounds were evaluated from the experimental data of the heat capacities over the temperature range of T = (6–300) K. The deviation of experimental points from fitting curves obtained on the basis of Debye's theory. The overview on low-temperature heat capacity and standard thermodynamic properties of cation-ordered layered perovskite-like titanates NaLnTiO4 and A2Ln2Ti3O10 (A=H, Na, K; Ln=La, Nd, Gd) is present.
KW - Adiabatic calorimetry
KW - Heat capacity
KW - Layered perovskite-like oxides
KW - Protonated forms
KW - Standard thermodynamic functions
KW - MOBILITY
KW - K2LA2TI3O10
KW - RANGE
UR - http://www.scopus.com/inward/record.url?scp=85079232819&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/6ee3e964-cbbd-315c-a824-ef9f0cf65e94/
U2 - 10.1016/j.tca.2020.178533
DO - 10.1016/j.tca.2020.178533
M3 - Article
AN - SCOPUS:85079232819
VL - 686
JO - Thermochimica Acta
JF - Thermochimica Acta
SN - 0040-6031
M1 - 178533
ER -
ID: 70816895