Influence of Interactions in Solutions on the Solid Phase Formation in Ternary Water-Salt Systems

M.Yu Skripkin, L.V. Chernykh, O.N. Pestova, V.E. Baranauskaite, K.A. Burkov, I.V. Zamyatin, L.V. Stepakova, I.M. Gusev, A.O. Gorbunov, N.A. Bogachev, G.L. Starova

Результат исследований: Научные публикации в периодических изданияхстатья

Выдержка

The influence of ionic interactions in ternary aqueous and aqueous-organic solutions of metal halides on the structure of the solid phases in equilibrium with the solutions is analyzed. An original classification of double and complex salts, reflecting the peculiarities of their structure, is given. The conditions for the formation of various types of these compounds are determined. The factors that determine the preservation of the metal ion surrounding during the solution-solid phase transition are revealed.

Язык оригиналаанглийский
Страницы (с-по)1085-1101
ЖурналRussian Journal of General Chemistry
Том89
Номер выпуска6
DOI
СостояниеОпубликовано - 1 июн 2019

Отпечаток

Saline water
Metal halides
Metal ions
Solid solutions
Salts
Phase transitions

Предметные области Scopus

  • Химия (все)

Цитировать

Skripkin, M.Yu ; Chernykh, L.V. ; Pestova, O.N. ; Baranauskaite, V.E. ; Burkov, K.A. ; Zamyatin, I.V. ; Stepakova, L.V. ; Gusev, I.M. ; Gorbunov, A.O. ; Bogachev, N.A. ; Starova, G.L. / Influence of Interactions in Solutions on the Solid Phase Formation in Ternary Water-Salt Systems. В: Russian Journal of General Chemistry. 2019 ; Том 89, № 6. стр. 1085-1101.
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Skripkin, MY, Chernykh, LV, Pestova, ON, Baranauskaite, VE, Burkov, KA, Zamyatin, IV, Stepakova, LV, Gusev, IM, Gorbunov, AO, Bogachev, NA & Starova, GL 2019, 'Influence of Interactions in Solutions on the Solid Phase Formation in Ternary Water-Salt Systems', Russian Journal of General Chemistry, том. 89, № 6, стр. 1085-1101. https://doi.org/10.1134/S1070363219060033

Influence of Interactions in Solutions on the Solid Phase Formation in Ternary Water-Salt Systems. / Skripkin, M.Yu; Chernykh, L.V.; Pestova, O.N.; Baranauskaite, V.E.; Burkov, K.A.; Zamyatin, I.V.; Stepakova, L.V.; Gusev, I.M.; Gorbunov, A.O.; Bogachev, N.A.; Starova, G.L.

В: Russian Journal of General Chemistry, Том 89, № 6, 01.06.2019, стр. 1085-1101.

Результат исследований: Научные публикации в периодических изданияхстатья

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T1 - Influence of Interactions in Solutions on the Solid Phase Formation in Ternary Water-Salt Systems

AU - Skripkin, M.Yu

AU - Chernykh, L.V.

AU - Pestova, O.N.

AU - Baranauskaite, V.E.

AU - Burkov, K.A.

AU - Zamyatin, I.V.

AU - Stepakova, L.V.

AU - Gusev, I.M.

AU - Gorbunov, A.O.

AU - Bogachev, N.A.

AU - Starova, G.L.

PY - 2019/6/1

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N2 - The influence of ionic interactions in ternary aqueous and aqueous-organic solutions of metal halides on the structure of the solid phases in equilibrium with the solutions is analyzed. An original classification of double and complex salts, reflecting the peculiarities of their structure, is given. The conditions for the formation of various types of these compounds are determined. The factors that determine the preservation of the metal ion surrounding during the solution-solid phase transition are revealed.

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KW - aqueous and water-organic solutions

KW - complex salts

KW - crystalline solvates

KW - double salts

KW - metal halides

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