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“Hydration Shells” of CH2 Groups of ω-Amino Acids as Studied by Deuteron NMR Relaxation. / Rabdano, Sevastyan O.; Donets, Alexey V.; Vovk, Mikhail A.; Michel, Dieter; Chizhik, Vladimir I.

в: Journal of Physical Chemistry B, Том 119, № 42, 2015, стр. 13358–13366.

Результаты исследований: Научные публикации в периодических изданиях › статья

Harvard

Rabdano, SO, Donets, AV, Vovk, MA, Michel, D & Chizhik, VI 2015, '“Hydration Shells” of CH2 Groups of ω-Amino Acids as Studied by Deuteron NMR Relaxation', Journal of Physical Chemistry B, Том. 119, № 42, стр. 13358–13366. https://doi.org/10.1021/acs.jpcb.5b06584

APA

Rabdano, S. O., Donets, A. V., Vovk, M. A., Michel, D., & Chizhik, V. I. (2015). “Hydration Shells” of CH2 Groups of ω-Amino Acids as Studied by Deuteron NMR Relaxation. Journal of Physical Chemistry B, 119(42), 13358–13366. https://doi.org/10.1021/acs.jpcb.5b06584

Vancouver

Rabdano SO, Donets AV, Vovk MA, Michel D, Chizhik VI. “Hydration Shells” of CH2 Groups of ω-Amino Acids as Studied by Deuteron NMR Relaxation. Journal of Physical Chemistry B. 2015;119(42):13358–13366. https://doi.org/10.1021/acs.jpcb.5b06584

Author

Rabdano, Sevastyan O. ; Donets, Alexey V. ; Vovk, Mikhail A. ; Michel, Dieter ; Chizhik, Vladimir I. / “Hydration Shells” of CH2 Groups of ω-Amino Acids as Studied by Deuteron NMR Relaxation. в: Journal of Physical Chemistry B. 2015 ; Том 119, № 42. стр. 13358–13366.

BibTeX

@article{2edb7be9256a443fa1f72f05fdae6436,
title = "“Hydration Shells” of CH2 Groups of ω-Amino Acids as Studied by Deuteron NMR Relaxation",
abstract = "{\textcopyright} 2015 American Chemical Society.Hydration phenomena play a very important role in various processes, in particular in biological systems. Water molecules in aqueous solutions of organic compounds can be distributed among the following substructures: (i) hydration shells of hydrophilic functional groups of molecules, (ii) water in the environment of nonpolar moieties, and (iii) bulk water. Up to now, the values of hydration parameters suggested for the description of various solutions of organic compounds were not thoroughly analyzed in the aspect of the consideration of the total molecular composition. The temperature and concentration dependences of relaxation rates of water deuterons were studied in a wide range of concentration and temperature in aqueous (D2O) solutions of a set of ω-amino acids. Assuming the coordination number of the CH2 group equal to 7, which was determined from quantum-chemical calculations, it was found that the rotational correlation times of water molecules near the methylene grou",
author = "Rabdano, {Sevastyan O.} and Donets, {Alexey V.} and Vovk, {Mikhail A.} and Dieter Michel and Chizhik, {Vladimir I.}",
year = "2015",
doi = "10.1021/acs.jpcb.5b06584",
language = "English",
volume = "119",
pages = "13358–13366",
journal = "Journal of Physical Chemistry B",
issn = "1520-6106",
publisher = "American Chemical Society",
number = "42",

}

RIS

TY - JOUR

T1 - “Hydration Shells” of CH2 Groups of ω-Amino Acids as Studied by Deuteron NMR Relaxation

AU - Rabdano, Sevastyan O.

AU - Donets, Alexey V.

AU - Vovk, Mikhail A.

AU - Michel, Dieter

AU - Chizhik, Vladimir I.

PY - 2015

Y1 - 2015

N2 - © 2015 American Chemical Society.Hydration phenomena play a very important role in various processes, in particular in biological systems. Water molecules in aqueous solutions of organic compounds can be distributed among the following substructures: (i) hydration shells of hydrophilic functional groups of molecules, (ii) water in the environment of nonpolar moieties, and (iii) bulk water. Up to now, the values of hydration parameters suggested for the description of various solutions of organic compounds were not thoroughly analyzed in the aspect of the consideration of the total molecular composition. The temperature and concentration dependences of relaxation rates of water deuterons were studied in a wide range of concentration and temperature in aqueous (D2O) solutions of a set of ω-amino acids. Assuming the coordination number of the CH2 group equal to 7, which was determined from quantum-chemical calculations, it was found that the rotational correlation times of water molecules near the methylene grou

AB - © 2015 American Chemical Society.Hydration phenomena play a very important role in various processes, in particular in biological systems. Water molecules in aqueous solutions of organic compounds can be distributed among the following substructures: (i) hydration shells of hydrophilic functional groups of molecules, (ii) water in the environment of nonpolar moieties, and (iii) bulk water. Up to now, the values of hydration parameters suggested for the description of various solutions of organic compounds were not thoroughly analyzed in the aspect of the consideration of the total molecular composition. The temperature and concentration dependences of relaxation rates of water deuterons were studied in a wide range of concentration and temperature in aqueous (D2O) solutions of a set of ω-amino acids. Assuming the coordination number of the CH2 group equal to 7, which was determined from quantum-chemical calculations, it was found that the rotational correlation times of water molecules near the methylene grou

U2 - 10.1021/acs.jpcb.5b06584

DO - 10.1021/acs.jpcb.5b06584

M3 - Article

VL - 119

SP - 13358

EP - 13366

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

SN - 1520-6106

IS - 42

ER -

ID: 4014991