Heat capacity and standard thermodynamic functions of the fullerenol C60(OH)24

Alexey V. Markin, Yanina S. Samosudova, Timofey G. Ogurtsov, Natalia N. Smirnova, Sergei V. Ageev, Nikita E. Podolsky, Andrey V. Petrov, Igor V. Murin, Konstantin N. Semenov

Результат исследований: Научные публикации в периодических изданияхстатьярецензирование

1 Цитирования (Scopus)

Аннотация

In the present investigation, the heat capacity of fullerenol C60(OH)24 was measured by precision adiabatic and differential scanning calorimetry over the temperature range from T = (6 to 670) K. The keto-enol tautomerism was revealed in the temperature range T = (355–575) K and enthalpy of transition was determined. The standard thermodynamic functions: molar heat capacity Cp°, enthalpy [H°(T) − H°(0)], entropy S°(T), and Gibbs energy [G°(T) − H°(0)] of the fullerenol were determined over the temperature range from T = (6 to 350) K from the obtained experimental results. Also, DFT calculations of the heat capacities were performed. The standard thermodynamic properties of the investigated fullerenol were compared to other fullerene derivatives.

Язык оригиналаанглийский
Номер статьи106192
ЖурналJournal of Chemical Thermodynamics
Том149
DOI
СостояниеОпубликовано - окт 2020

Предметные области Scopus

  • Атомная и молекулярная физика и оптика
  • Материаловедение (все)
  • Физическая и теоретическая химия

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