Gold(I)-Catalyzed Oxidation of Acyl Acetylenes to Vicinal Tricarbonyls

Результат исследований: Научные публикации в периодических изданияхстатья

Выдержка

Efficient gold(I)-catalyzed oxidation of COR2-functionalized internal alkynes to vicinal tricarbonyl compounds by 2,6-dichloropyridine N-oxide proceeds under mild conditions (DCM, rt). This catalytic reaction provides a good to excellent yielding route to diverse tricarbonyls such as α,β-diketoesters, 1,2,3-triketones, and α,β-diketoamides. The utility of these compounds was also demonstrated by facile one-pot synthesis of important azaheterocyclic systems.

Язык оригиналаанглийский
ЖурналOrganic Letters
DOI
СостояниеОпубликовано - 1 янв 2019

Отпечаток

Alkynes
alkynes
acetylene
Gold
routes
gold
Oxidation
oxidation
oxides
synthesis
2,6-dichloropyridine N-oxide

Предметные области Scopus

  • Биохимия
  • Физическая и теоретическая химия
  • Органическая химия

Цитировать

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abstract = "Efficient gold(I)-catalyzed oxidation of COR2-functionalized internal alkynes to vicinal tricarbonyl compounds by 2,6-dichloropyridine N-oxide proceeds under mild conditions (DCM, rt). This catalytic reaction provides a good to excellent yielding route to diverse tricarbonyls such as α,β-diketoesters, 1,2,3-triketones, and α,β-diketoamides. The utility of these compounds was also demonstrated by facile one-pot synthesis of important azaheterocyclic systems.",
author = "Dubovtsev, {Alexey Yu} and Dar'In, {Dmitry V.} and Kukushkin, {Vadim Yu}",
year = "2019",
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doi = "10.1021/acs.orglett.9b01297",
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journal = "Organic Letters",
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Gold(I)-Catalyzed Oxidation of Acyl Acetylenes to Vicinal Tricarbonyls. / Dubovtsev, Alexey Yu; Dar'In, Dmitry V.; Kukushkin, Vadim Yu.

В: Organic Letters, 01.01.2019.

Результат исследований: Научные публикации в периодических изданияхстатья

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AB - Efficient gold(I)-catalyzed oxidation of COR2-functionalized internal alkynes to vicinal tricarbonyl compounds by 2,6-dichloropyridine N-oxide proceeds under mild conditions (DCM, rt). This catalytic reaction provides a good to excellent yielding route to diverse tricarbonyls such as α,β-diketoesters, 1,2,3-triketones, and α,β-diketoamides. The utility of these compounds was also demonstrated by facile one-pot synthesis of important azaheterocyclic systems.

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