Effect of composition on character of defect formation and ion transport in (1–x)[Ca1–yYb y 2+ ]Yb 2 3+ S4–δ–xYb2S3 phases

B. A. Ananchenko, A. O. Myakishev, E. V. Kosheleva, I. V. Murin

Результат исследований: Научные публикации в периодических изданияхстатья

2 Цитирования (Scopus)

Выдержка

Structural features of solid solutions based on CaYb2S4 (the Yb3S4 structural type) are studied using the methods of Rietveld full-profile analysis, measurement of pycnometric density, and thermal analysis in vacuum with simultaneous study of variation of the elementary cell parameters. Conductivity of samples with different doping additive content are studied in the medium of argon and in the hydrogen sulfidecontaining medium using the impedance technique. Different mechanisms of defect formation are analyzed as dependent on the doping degree.

Язык оригиналаанглийский
Страницы (с-по)799-807
Число страниц9
ЖурналRussian Journal of Electrochemistry
Том53
Номер выпуска8
DOI
СостояниеОпубликовано - 1 авг 2017

Отпечаток

Doping (additives)
Ions
Defects
Argon
Chemical analysis
Thermoanalysis
Hydrogen
Solid solutions
Vacuum

Предметные области Scopus

  • Электрохимия

Цитировать

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abstract = "Structural features of solid solutions based on CaYb2S4 (the Yb3S4 structural type) are studied using the methods of Rietveld full-profile analysis, measurement of pycnometric density, and thermal analysis in vacuum with simultaneous study of variation of the elementary cell parameters. Conductivity of samples with different doping additive content are studied in the medium of argon and in the hydrogen sulfidecontaining medium using the impedance technique. Different mechanisms of defect formation are analyzed as dependent on the doping degree.",
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Effect of composition on character of defect formation and ion transport in (1–x)[Ca1–yYb y 2+ ]Yb 2 3+ S4–δ–xYb2S3 phases. / Ananchenko, B. A.; Myakishev, A. O.; Kosheleva, E. V.; Murin, I. V.

В: Russian Journal of Electrochemistry, Том 53, № 8, 01.08.2017, стр. 799-807.

Результат исследований: Научные публикации в периодических изданияхстатья

TY - JOUR

T1 - Effect of composition on character of defect formation and ion transport in (1–x)[Ca1–yYb y 2+ ]Yb 2 3+ S4–δ–xYb2S3 phases

AU - Ananchenko, B. A.

AU - Myakishev, A. O.

AU - Kosheleva, E. V.

AU - Murin, I. V.

PY - 2017/8/1

Y1 - 2017/8/1

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AB - Structural features of solid solutions based on CaYb2S4 (the Yb3S4 structural type) are studied using the methods of Rietveld full-profile analysis, measurement of pycnometric density, and thermal analysis in vacuum with simultaneous study of variation of the elementary cell parameters. Conductivity of samples with different doping additive content are studied in the medium of argon and in the hydrogen sulfidecontaining medium using the impedance technique. Different mechanisms of defect formation are analyzed as dependent on the doping degree.

KW - defect formation

KW - impedance spectroscopy

KW - Rietveld full-profile analysis

KW - sulfide-conducting electrolytes

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