Dependence of stability of the polymerizesd nickel complexes with schiff bases on the structure of the ligand diimine bridge

Результат исследований: Публикации в книгах, отчётах, сборниках, трудах конференцийстатья в сборнике материалов конференции

1 цитирование (Scopus)

Выдержка

In this work, the influence of substituents in the structure of the diimine bridge of nickel polymer complexes with salen-type ligands on the rate of loss of their electroactivity in dried and water-containing electrolyte solutions was studied. It is shown that the presence of the four methyl groups, which leaves the complex plane, can significantly reduce the rate of electroactivity loss during cycling in a water-containing electrolyte (residual capacity of 37% relative to the initial one after 50 cycles) compared to unsubstituted poly[Ni(salen)] (residual capacity of 15%), and complexes containing only one methyl group and methyl groups in alpha positions of the diimine bridge (retaining of 5% and 0% of residual capacity by after 50 cycles, respectively). It was shown that in all cases, when cycling in a water-containing electrolyte, in parallel with the loss of capacity of the polymer films, their mass increases.

Язык оригиналаанглийский
Название основной публикацииECS Transactions
РедакторыJiri Vondrak, F. Klein, Marie Sedlarikova
ИздательThe Electrochemical Society
Страницы167-177
Число страниц11
Том87
Издание1
ISBN (электронное издание)9781607685395
DOI
СостояниеОпубликовано - 1 янв 2018
Событие19th International Conference on Advanced Batteries, Accumulators and Fuel Cells, ABAF 2018 - Brno, Чехия
Продолжительность: 26 авг 201829 авг 2018

Конференция

Конференция19th International Conference on Advanced Batteries, Accumulators and Fuel Cells, ABAF 2018
СтранаЧехия
ГородBrno
Период26/08/1829/08/18

Отпечаток

Ligands
Electrolytes
Nickel
Water
Polymer films
Polymers

Предметные области Scopus

  • Технология (все)

Цитировать

Алексеева, Елена Валерьевна ; Ershov, V. A. ; Konev, A. S. ; Levin, O. V. / Dependence of stability of the polymerizesd nickel complexes with schiff bases on the structure of the ligand diimine bridge. ECS Transactions. редактор / Jiri Vondrak ; F. Klein ; Marie Sedlarikova. Том 87 1. ред. The Electrochemical Society, 2018. стр. 167-177
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abstract = "In this work, the influence of substituents in the structure of the diimine bridge of nickel polymer complexes with salen-type ligands on the rate of loss of their electroactivity in dried and water-containing electrolyte solutions was studied. It is shown that the presence of the four methyl groups, which leaves the complex plane, can significantly reduce the rate of electroactivity loss during cycling in a water-containing electrolyte (residual capacity of 37{\%} relative to the initial one after 50 cycles) compared to unsubstituted poly[Ni(salen)] (residual capacity of 15{\%}), and complexes containing only one methyl group and methyl groups in alpha positions of the diimine bridge (retaining of 5{\%} and 0{\%} of residual capacity by after 50 cycles, respectively). It was shown that in all cases, when cycling in a water-containing electrolyte, in parallel with the loss of capacity of the polymer films, their mass increases.",
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Алексеева, ЕВ, Ershov, VA, Konev, AS & Levin, OV 2018, Dependence of stability of the polymerizesd nickel complexes with schiff bases on the structure of the ligand diimine bridge. в J Vondrak, F Klein & M Sedlarikova (ред.), ECS Transactions. 1 ред., том. 87, The Electrochemical Society, стр. 167-177, Brno, Чехия, 26/08/18. https://doi.org/10.1149/08701.0167ecst

Dependence of stability of the polymerizesd nickel complexes with schiff bases on the structure of the ligand diimine bridge. / Алексеева, Елена Валерьевна; Ershov, V. A.; Konev, A. S.; Levin, O. V.

ECS Transactions. ред. / Jiri Vondrak; F. Klein; Marie Sedlarikova. Том 87 1. ред. The Electrochemical Society, 2018. стр. 167-177.

Результат исследований: Публикации в книгах, отчётах, сборниках, трудах конференцийстатья в сборнике материалов конференции

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N2 - In this work, the influence of substituents in the structure of the diimine bridge of nickel polymer complexes with salen-type ligands on the rate of loss of their electroactivity in dried and water-containing electrolyte solutions was studied. It is shown that the presence of the four methyl groups, which leaves the complex plane, can significantly reduce the rate of electroactivity loss during cycling in a water-containing electrolyte (residual capacity of 37% relative to the initial one after 50 cycles) compared to unsubstituted poly[Ni(salen)] (residual capacity of 15%), and complexes containing only one methyl group and methyl groups in alpha positions of the diimine bridge (retaining of 5% and 0% of residual capacity by after 50 cycles, respectively). It was shown that in all cases, when cycling in a water-containing electrolyte, in parallel with the loss of capacity of the polymer films, their mass increases.

AB - In this work, the influence of substituents in the structure of the diimine bridge of nickel polymer complexes with salen-type ligands on the rate of loss of their electroactivity in dried and water-containing electrolyte solutions was studied. It is shown that the presence of the four methyl groups, which leaves the complex plane, can significantly reduce the rate of electroactivity loss during cycling in a water-containing electrolyte (residual capacity of 37% relative to the initial one after 50 cycles) compared to unsubstituted poly[Ni(salen)] (residual capacity of 15%), and complexes containing only one methyl group and methyl groups in alpha positions of the diimine bridge (retaining of 5% and 0% of residual capacity by after 50 cycles, respectively). It was shown that in all cases, when cycling in a water-containing electrolyte, in parallel with the loss of capacity of the polymer films, their mass increases.

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Алексеева ЕВ, Ershov VA, Konev AS, Levin OV. Dependence of stability of the polymerizesd nickel complexes with schiff bases on the structure of the ligand diimine bridge. В Vondrak J, Klein F, Sedlarikova M, редакторы, ECS Transactions. 1 ред. Том 87. The Electrochemical Society. 2018. стр. 167-177 https://doi.org/10.1149/08701.0167ecst